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- W2887887632 abstract "A sequential production of levulinic acid (LA) and porous carbon material (CM) from cellulose was conducted by a two-step process. The cellulose was first acid hydrolyzed, and the preferred reaction conditions required a severity factor of 4.0⁻4.5, in which the yields of LA, formic acid, and solid residue were 38 ± 3 wt%, 17 ± 3 wt%, and 15 ± 3 wt%, respectively. The solid residue was further used for CM preparation through pyrolysis, with or without ZnCl₂ activation. The ZnCl₂ activation promoted the formation of CMs with improved thermal stability, high surface area (1184⁻2510 m²/g), and excellent phenol adsorption capacity (136⁻172 mg/g). The used CM can be easily regenerated by a simple methanol Soxhlet extraction process, and a comparable phenol adsorption capacity of 97 mg/g was maintained for the 5th reusing. Finally, 100 g cellulose produced 40.5 g LA, 18.9 g formic acid and 8.5 g porous CM, with a total carbon utilization ratio reaching 74.4%." @default.
- W2887887632 created "2018-08-22" @default.
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- W2887887632 date "2018-08-11" @default.
- W2887887632 modified "2023-09-29" @default.
- W2887887632 title "Sequential Production of Levulinic Acid and Porous Carbon Material from Cellulose" @default.
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- W2887887632 doi "https://doi.org/10.3390/ma11081408" @default.
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