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- W2887934730 abstract "Abstract A novel nano phosphorus and nitrogen based flame retardant, i.e. magnesium amino-tris-(methylenephosphonate) (Mg-AMP) was synthesized and characterized by Fourier-transform infrared and X-ray diffraction spectroscopies, transmission electronic microscopy, and thermogravimetric analysis (TGA). Flame retarded rigid polyurethane (RPU) foams filled with nano Mg-AMP and expandable graphite (EG) were prepared, and a synergistic effect in flame retardancy between Mg-AMP and EG in RPU foam was observed. The RPU foam containing 12 wt% EG and 3 wt% Mg-AMP (sample RPU/12EG/3Mg-AMP) reached a V0 rating in vertical UL-94 test with a limiting oxygen index of 29.5%. The peak heat release rate and total heat release of sample RPU/12EG/3Mg-AMP were obviously decreased by 52.4 and 42.9%, respectively compared with the foam with 15 wt% EG (sample RPU/15EG). Moreover, the compressive strength of sample RPU/12EG/3Mg-AMP was 35% higher than that of sample RPU/15EG, and the thermal conductivity of the former was lower than the one of the latter. TGA results indicated that the combination of Mg-AMP and EG clearly improved the thermal stability and yield of residual char of RPU foam." @default.
- W2887934730 created "2018-08-22" @default.
- W2887934730 creator A5041041396 @default.
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- W2887934730 date "2018-11-01" @default.
- W2887934730 modified "2023-09-24" @default.
- W2887934730 title "Synergistic effect of nano magnesium amino-tris-(methylenephosphonate) and expandable graphite on improving flame retardant, mechanical and thermal insulating properties of rigid polyurethane foam" @default.
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- W2887934730 doi "https://doi.org/10.1016/j.matchemphys.2018.08.010" @default.
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