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- W2887937008 abstract "Linear elastic Hookean solids can be strong but become brittle in general as their strength-to-modulus ratio is higher about 1/100 due to the well-known inverse strength-ductility relationship. Combined with the first-order reversible martensitc transformation, they can be functional but their mechanical and functional properties are sensitive to temperature, for example, superelasticity and zero/negative thermal expansion are limited in a narrow temperature range of about 100 Kelvin. Here we report a group of titanium alloys which are strong, ductile, flexible together with superelasticity and tunable thermal expansion from positive, via zero, to negative across a wide temperature range from below 4.2 K to 625 K. This is attributed to its nonlinear elasticity obeying a high-order Hooke's law due to a continuous and reversible atomic rearrangement at a large scale up to phase transition strain. Such novel mechanism distinguishes completely from the previous elastic and martensitic mechanisms ruled by Poisson ratio and sharp crystal structure change, respectively. We demonstrate that the atomic-level mechanism is organized adaptively by a nanoscale compositional modulation, which is created by a spinodal decomposition. These findings pave a way to design new solids through a nanoscale periodical distribution in chemistry." @default.
- W2887937008 created "2018-08-22" @default.
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- W2887937008 date "2018-10-01" @default.
- W2887937008 modified "2023-09-27" @default.
- W2887937008 title "Continuous and reversible atomic rearrangement in a multifunctional titanium alloy" @default.
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- W2887937008 doi "https://doi.org/10.1016/j.mtla.2018.08.013" @default.
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