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- W2887972364 abstract "The compounds EtOC([double bond, length as m-dash]O)CHNNPR3 (R = Ph 1, Cy 2, tBu 3) were prepared via the reactions of the diazomethane and a phosphine. In subsequent reactions with B(C6F5)3, the compounds 2 and 3 are shown to exhibit Lewis basicity at the carbonyl oxygen affording EtOC([double bond, length as m-dash]O(B(C6F5)3))CHNNPR3 (R = Cy 5, tBu 6). Reactions of 5 and 6 with water or phenol illustrated the Brønsted basicity at the nitrogen atom adjacent phosphorus, affording the compounds, [EtOC([double bond, length as m-dash]O)CHNNHPR3][HOB(C6F5)3] (R = Cy 7, tBu 8) and [EtOC([double bond, length as m-dash]O)CHNNHPR3][PhOB(C6F5)3] (R = Cy 9, tBu 10), respectively. The formulation of these products is confirmed via spectroscopic and crystallographic studies, and insight is garnered from computations." @default.
- W2887972364 created "2018-08-22" @default.
- W2887972364 creator A5005757075 @default.
- W2887972364 creator A5008184387 @default.
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- W2887972364 date "2018-01-01" @default.
- W2887972364 modified "2023-10-18" @default.
- W2887972364 title "Lewis and Brønsted basicity of phosphine-diazomethane derivatives" @default.
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- W2887972364 doi "https://doi.org/10.1039/c8dt02420k" @default.
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