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• W2888025587 abstract "Negative thermal expansion materials, such as zirconium vanadate (ZrV2O7), have attracted considerable interest due to potential applications on tailoring the coefficient of thermal expansion. This paper studied ZrV2O7 transport properties. ZrV2O7 had electrical conductivity σ = 3.56 × 10−3 S/cm at 573 K, significantly larger than other NTE ceramics, such as Sc2W3O12, and activation energy Ea = 0.319 eV, calculated from Arrhenius plots for total conductivity. Resistance decreased as temperature increased from room temperature to 400 K, ascribed to increasing carrier concentration and small lattice constant. Conductivity rapidly increased as temperature increased from 423 to 573 K, but high electron scattering probability led to little further conductivity changes from 573 to 673 K. Dielectric constant = 15.8 at high frequency (> 10 MHz), which could enable significant enhancement for high frequency electronic devices." @default.
• W2888025587 created "2018-08-31" @default.
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• W2888025587 date "2018-12-01" @default.
• W2888025587 modified "2023-10-16" @default.
• W2888025587 title "Electrical properties and dielectric relaxation behavior of zirconium vanadate" @default.
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• W2888025587 doi "https://doi.org/10.1016/j.ceramint.2018.08.244" @default.
• W2888025587 hasPublicationYear "2018" @default.
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