FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2888034802> ?p ?o ?g. }

• W2888034802 endingPage "11577" @default.
• W2888034802 startingPage "11569" @default.
• W2888034802 abstract "We bring together magnetization, infrared spectroscopy, and lattice dynamics calculations to uncover the magnetic field-temperature ( B- T) phase diagrams and vibrational properties of the [(CH3)2NH2] M(HCOO)3 ( M = Mn2+, Co2+, Ni2+) family of multiferroics. While the magnetically driven transition to the fully saturated state in [(CH3)2NH2]Mn(HCOO)3 takes place at 15.3 T, substitution with Ni or Co drives the critical fields up toward 100 T, an unexpectedly high energy scale for these compounds. Analysis of the infrared spectrum of the Mn and Ni compounds across TC reveals doublet splitting of the formate bending mode which functions as an order parameter of the ferroelectric transition. By contrast, [(CH3)2NH2]Co(HCOO)3 reveals a surprising framework rigidity across the order-disorder transition due to modest distortions around the Co2+ centers. The transition to the ferroelectric state is thus driven by the dimethylammonium cation freezing and the resulting hydrogen bonding. Under applied field, the Mn (and most likely, the Ni) compounds engage the formate bending mode to facilitate the transition to their fully saturated magnetic states, whereas the Co complex adopts a different mechanism involving formate stretching distortions to lower the overall magnetic energy. Similar structure-property relations involving substitution of transition-metal centers and control of the flexible molecular architecture are likely to exist in other molecule-based multiferroics." @default.
• W2888034802 created "2018-08-31" @default.
• W2888034802 creator A5000183293 @default.
• W2888034802 creator A5012677271 @default.
• W2888034802 creator A5028348006 @default.
• W2888034802 creator A5032791805 @default.
• W2888034802 creator A5035092600 @default.
• W2888034802 creator A5042983462 @default.
• W2888034802 creator A5048618157 @default.
• W2888034802 creator A5061163951 @default.
• W2888034802 creator A5070538258 @default.
• W2888034802 creator A5076058110 @default.
• W2888034802 creator A5088722533 @default.
• W2888034802 date "2018-08-24" @default.
• W2888034802 modified "2023-10-07" @default.
• W2888034802 title "Structure–Property Relations in Multiferroic [(CH₃)₂NH₂]<i>M</i>(HCOO)₃ (<i>M</i> = Mn, Co, Ni)" @default.
• W2888034802 cites W1575492558 @default.
• W2888034802 cites W1957280626 @default.
• W2888034802 cites W1970127494 @default.
• W2888034802 cites W1978673622 @default.
• W2888034802 cites W1978941497 @default.
• W2888034802 cites W1979544533 @default.
• W2888034802 cites W1981368803 @default.
• W2888034802 cites W1996404541 @default.
• W2888034802 cites W2030717826 @default.
• W2888034802 cites W2046369808 @default.
• W2888034802 cites W2051619086 @default.
• W2888034802 cites W2059233014 @default.
• W2888034802 cites W2059841912 @default.
• W2888034802 cites W2069177212 @default.
• W2888034802 cites W2078882059 @default.
• W2888034802 cites W2083222334 @default.
• W2888034802 cites W2084551119 @default.
• W2888034802 cites W2092747881 @default.
• W2888034802 cites W2092911179 @default.
• W2888034802 cites W2109210841 @default.
• W2888034802 cites W2121429237 @default.
• W2888034802 cites W2125392482 @default.
• W2888034802 cites W2130386238 @default.
• W2888034802 cites W2141919336 @default.
• W2888034802 cites W2150061993 @default.
• W2888034802 cites W2157058142 @default.
• W2888034802 cites W2168615836 @default.
• W2888034802 cites W2197804376 @default.
• W2888034802 cites W2210940738 @default.
• W2888034802 cites W2229408209 @default.
• W2888034802 cites W2261120085 @default.
• W2888034802 cites W2291899032 @default.
• W2888034802 cites W2312382593 @default.
• W2888034802 cites W2312790604 @default.
• W2888034802 cites W2318491733 @default.
• W2888034802 cites W2319547297 @default.
• W2888034802 cites W2332576576 @default.
• W2888034802 cites W2470061049 @default.
• W2888034802 cites W2517842268 @default.
• W2888034802 cites W2522391439 @default.
• W2888034802 cites W2525372591 @default.
• W2888034802 cites W2551185961 @default.
• W2888034802 cites W2573266805 @default.
• W2888034802 cites W2579729659 @default.
• W2888034802 cites W2600528565 @default.
• W2888034802 cites W2756476825 @default.
• W2888034802 cites W2770073872 @default.
• W2888034802 cites W2788536056 @default.
• W2888034802 cites W3100164847 @default.
• W2888034802 cites W3102524179 @default.
• W2888034802 cites W3122531413 @default.
• W2888034802 cites W4320288075 @default.
• W2888034802 doi "https://doi.org/10.1021/acs.inorgchem.8b01609" @default.
• W2888034802 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30141625" @default.
• W2888034802 hasPublicationYear "2018" @default.
• W2888034802 type Work @default.
• W2888034802 sameAs 2888034802 @default.
• W2888034802 citedByCount "15" @default.
• W2888034802 countsByYear W28880348022019 @default.
• W2888034802 countsByYear W28880348022020 @default.
• W2888034802 countsByYear W28880348022021 @default.
• W2888034802 countsByYear W28880348022022 @default.
• W2888034802 countsByYear W28880348022023 @default.
• W2888034802 crossrefType "journal-article" @default.
• W2888034802 hasAuthorship W2888034802A5000183293 @default.
• W2888034802 hasAuthorship W2888034802A5012677271 @default.
• W2888034802 hasAuthorship W2888034802A5028348006 @default.
• W2888034802 hasAuthorship W2888034802A5032791805 @default.
• W2888034802 hasAuthorship W2888034802A5035092600 @default.
• W2888034802 hasAuthorship W2888034802A5042983462 @default.
• W2888034802 hasAuthorship W2888034802A5048618157 @default.
• W2888034802 hasAuthorship W2888034802A5061163951 @default.
• W2888034802 hasAuthorship W2888034802A5070538258 @default.
• W2888034802 hasAuthorship W2888034802A5076058110 @default.
• W2888034802 hasAuthorship W2888034802A5088722533 @default.
• W2888034802 hasBestOaLocation W28880348022 @default.
• W2888034802 hasConcept C106773901 @default.
• W2888034802 hasConcept C115260700 @default.
• W2888034802 hasConcept C121332964 @default.
• W2888034802 hasConcept C123266903 @default.
• W2888034802 hasConcept C133386390 @default.
• W2888034802 hasConcept C149288129 @default.

• next