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- W2888229449 abstract "A series of ceramic samples were prepared and characterized at 1400 °C in the BaO-TiO2-YO1.5 system. The obtained experimental results were adopted to the present thermodynamic evaluation to derive a set of thermodynamic database for the BaO-TiO2-YO1.5 system. The database was constructed by the CALPHAD method where the binary parameters from BaO-TiO2 and TiO2-YO1.5 systems were re-optimized, those from the BaO-YO1.5 system were simulated by our previous assessments. Thermodynamics descriptions of all liquid and terminal solid solution phases were treated by the substitutional solution model, the H-BaTiO3 (BaTiO3, hexagonal structure) and C-BaTiO3 (BaTiO3, cubic structure) were described by the compound energy formalism model, and other binary intermediate phases were treated as the stoichiometric compounds. Finally, some thermodynamic diagrams were calculated and compared with the experimental results. Good agreement between present calculations and the experimental results demonstrates that the present thermodynamic database is self-consistent and credible." @default.
- W2888229449 created "2018-08-31" @default.
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- W2888229449 date "2018-12-01" @default.
- W2888229449 modified "2023-10-14" @default.
- W2888229449 title "Phase equilibria and thermodynamic evaluation of BaO-TiO2-YO1.5 system" @default.
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- W2888229449 doi "https://doi.org/10.1016/j.jeurceramsoc.2018.08.028" @default.
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