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- W2888550597 abstract "The increasing importance of enzyme mimics in organic synthesis inspired us to design a novel biomimetic synthesis of β-carboline alkaloids directly from tryptophan and a second amino acid. This novel one-pot protocol utilizes abundant and readily available starting materials and thus presents a green and user-friendly alternative to conventional methods that rely on stepwise synthesis. Driven by molecular iodine and TFA, decarboxylation, deamination, Pictet–Spengler reaction, and oxidation reactions proceeded sequentially, transforming biomass amino acids into value-added alkaloid motifs." @default.
- W2888550597 created "2018-08-31" @default.
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- W2888550597 date "2018-08-22" @default.
- W2888550597 modified "2023-10-14" @default.
- W2888550597 title "Direct Biomimetic Synthesis of β-Carboline Alkaloids from Two Amino Acids" @default.
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- W2888550597 doi "https://doi.org/10.1021/acs.joc.8b01668" @default.
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