Matches in SemOpenAlex for { <https://semopenalex.org/work/W2888620579> ?p ?o ?g. }
- W2888620579 endingPage "1800454" @default.
- W2888620579 startingPage "1800454" @default.
- W2888620579 abstract "Chirality-tunable supramolecular metallacycles containing two light-responsive dithienylethene units and two chiral 1,1′-bi-2-naphthol (BINOL) units have been successfully constructed via coordination-driven self-assembly. These new metallacycles are well-characterized with 1D multinuclear NMR (1H and 31P NMR), 2D 1H-1H COSY and DOSY, ESI-TOF-MS, and PM6 semiempirical molecular orbital methods. Interestingly, upon irradiation with ultraviolet and visible light, the conformation of these metallacycles can undergo reversible transformation between ring-open and ring-closed forms accompanied with the obvious change of CD signals. Further investigation reveals that the photoisomerization of the dithienylethene moieties induces the change in the dihedral angle of the binaphthyl rings, thus leading to the chiral modulation of supramolecular metallacycles. Thus, this study provides very few examples of the light-induced chirality-tunable metallosupramolecular assemblies, which may find potential application in mimicking the function of natural systems in the future." @default.
- W2888620579 created "2018-08-31" @default.
- W2888620579 creator A5037909012 @default.
- W2888620579 creator A5039091156 @default.
- W2888620579 creator A5040398298 @default.
- W2888620579 creator A5042973046 @default.
- W2888620579 creator A5053429303 @default.
- W2888620579 creator A5056411306 @default.
- W2888620579 creator A5065125338 @default.
- W2888620579 creator A5074044851 @default.
- W2888620579 creator A5090385351 @default.
- W2888620579 date "2018-08-24" @default.
- W2888620579 modified "2023-09-24" @default.
- W2888620579 title "Photoresponsive Chirality-Tunable Supramolecular Metallacycles" @default.
- W2888620579 cites W1250929640 @default.
- W2888620579 cites W1963531331 @default.
- W2888620579 cites W1965743698 @default.
- W2888620579 cites W1975192546 @default.
- W2888620579 cites W1995143652 @default.
- W2888620579 cites W1999109661 @default.
- W2888620579 cites W2007181893 @default.
- W2888620579 cites W2016466005 @default.
- W2888620579 cites W2017378513 @default.
- W2888620579 cites W2021516045 @default.
- W2888620579 cites W2030808222 @default.
- W2888620579 cites W2031876508 @default.
- W2888620579 cites W2041510494 @default.
- W2888620579 cites W2051433689 @default.
- W2888620579 cites W2059205902 @default.
- W2888620579 cites W2071750044 @default.
- W2888620579 cites W2088762585 @default.
- W2888620579 cites W2090329067 @default.
- W2888620579 cites W2094136184 @default.
- W2888620579 cites W2097109046 @default.
- W2888620579 cites W2097906140 @default.
- W2888620579 cites W2098433683 @default.
- W2888620579 cites W2108633598 @default.
- W2888620579 cites W2111741521 @default.
- W2888620579 cites W2118859363 @default.
- W2888620579 cites W2119007778 @default.
- W2888620579 cites W2123377379 @default.
- W2888620579 cites W2133413783 @default.
- W2888620579 cites W2134572781 @default.
- W2888620579 cites W2137489621 @default.
- W2888620579 cites W2139663676 @default.
- W2888620579 cites W2139688284 @default.
- W2888620579 cites W2143573474 @default.
- W2888620579 cites W2144682136 @default.
- W2888620579 cites W2145647599 @default.
- W2888620579 cites W2146469557 @default.
- W2888620579 cites W2147232138 @default.
- W2888620579 cites W2155437952 @default.
- W2888620579 cites W2156190700 @default.
- W2888620579 cites W2157562270 @default.
- W2888620579 cites W2238969507 @default.
- W2888620579 cites W2254463843 @default.
- W2888620579 cites W2258940614 @default.
- W2888620579 cites W2298724722 @default.
- W2888620579 cites W2299015718 @default.
- W2888620579 cites W2303660569 @default.
- W2888620579 cites W2309250595 @default.
- W2888620579 cites W2309894847 @default.
- W2888620579 cites W2310812958 @default.
- W2888620579 cites W2318897174 @default.
- W2888620579 cites W2319774976 @default.
- W2888620579 cites W2320531280 @default.
- W2888620579 cites W2320810972 @default.
- W2888620579 cites W2321077391 @default.
- W2888620579 cites W2322224545 @default.
- W2888620579 cites W2324625176 @default.
- W2888620579 cites W2329331364 @default.
- W2888620579 cites W2330354304 @default.
- W2888620579 cites W2331005047 @default.
- W2888620579 cites W2331276727 @default.
- W2888620579 cites W2331563258 @default.
- W2888620579 cites W2331995341 @default.
- W2888620579 cites W2332574343 @default.
- W2888620579 cites W2470751628 @default.
- W2888620579 cites W2471929598 @default.
- W2888620579 cites W2534278659 @default.
- W2888620579 cites W2577408501 @default.
- W2888620579 cites W2587584464 @default.
- W2888620579 cites W2609941096 @default.
- W2888620579 cites W2619367714 @default.
- W2888620579 cites W2620678439 @default.
- W2888620579 cites W2733710359 @default.
- W2888620579 cites W2752295367 @default.
- W2888620579 cites W2766553070 @default.
- W2888620579 cites W2769020740 @default.
- W2888620579 cites W2770648399 @default.
- W2888620579 cites W2780928194 @default.
- W2888620579 cites W2781488361 @default.
- W2888620579 cites W2795269519 @default.
- W2888620579 cites W2796058258 @default.
- W2888620579 cites W2952053244 @default.
- W2888620579 cites W2952450708 @default.
- W2888620579 doi "https://doi.org/10.1002/marc.201800454" @default.
- W2888620579 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30142240" @default.