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• W2888710652 abstract "Catalytic enantioselective functionalization of 2-pyrrolyl acetic acid with trichloromethyl enones using isothiourea catalysis is reported, leading to a range of stereodefined diesters and diamides after nucleophilic ring opening with either methanol or benzylamine (30 examples, up to >95:5 dr and >99:1 er). Subsequent intramolecular Friedel-Crafts reaction allows access to dihydroindolizinones in high yields and stereofidelity (6 examples, up to >95:5 dr and 99:1 er)." @default.
• W2888710652 created "2018-08-31" @default.
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• W2888710652 date "2018-08-24" @default.
• W2888710652 modified "2023-10-01" @default.
• W2888710652 title "Isothiourea-Catalyzed Enantioselective Functionalization of 2-Pyrrolyl Acetic Acid: Two-Step Synthesis of Stereodefined Dihydroindolizinones" @default.
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• W2888710652 doi "https://doi.org/10.1021/acs.orglett.8b02423" @default.
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