Matches in SemOpenAlex for { <https://semopenalex.org/work/W2888876639> ?p ?o ?g. }
- W2888876639 endingPage "11510" @default.
- W2888876639 startingPage "11498" @default.
- W2888876639 abstract "We explore here the structure-function relationship of the diheme cytochrome c using synthetic diheme analogs which serve as a convenient tool to investigate various aspects of Nature's sophisticated design in vitro. A large series of diiron ethane-bridged porphyrin dimers, both in the oxidized and the reduced states, are synthesized and their structural, chemical, and electrochemical properties have been scrutinized. Interestingly, the iron-to-iron nonbonding separation observed in such dihemes ranges from 9.49 to 10.06 Å which is very similar to the separation of 9.4 and 9.9 Å observed in the crystal structures of diheme cytochromes c isolated from Geobacter sulfurreducens and Haemophilus influenza, respectively. The FeIII/FeII redox couple in the diheme complex is shifted toward more positive than their monomeric analog. Present study unmasks the electronic structure and properties of diheme centers and also highlights the significance of their structural arrangement and axial ligand orientation, and heme-to-heme separation. The Atoms in Molecules (AIM) analysis suggests long-range attractive dispersion forces between the heme units for the observed structure and properties in dihemes." @default.
- W2888876639 created "2018-09-07" @default.
- W2888876639 creator A5044567213 @default.
- W2888876639 creator A5063450399 @default.
- W2888876639 creator A5068969801 @default.
- W2888876639 creator A5078685302 @default.
- W2888876639 date "2018-08-27" @default.
- W2888876639 modified "2023-09-24" @default.
- W2888876639 title "Diheme Cytochrome <i>c</i>: Structure–Function Correlation and Effect of Heme−Heme Interactions" @default.
- W2888876639 cites W1720991284 @default.
- W2888876639 cites W1867481768 @default.
- W2888876639 cites W1969538018 @default.
- W2888876639 cites W1970338292 @default.
- W2888876639 cites W1978092591 @default.
- W2888876639 cites W1978965855 @default.
- W2888876639 cites W1981995715 @default.
- W2888876639 cites W1983594091 @default.
- W2888876639 cites W1986960470 @default.
- W2888876639 cites W1991594337 @default.
- W2888876639 cites W1992864322 @default.
- W2888876639 cites W1993366463 @default.
- W2888876639 cites W1994719808 @default.
- W2888876639 cites W2005630792 @default.
- W2888876639 cites W2010105986 @default.
- W2888876639 cites W2016140160 @default.
- W2888876639 cites W2018295952 @default.
- W2888876639 cites W2019787060 @default.
- W2888876639 cites W2021770275 @default.
- W2888876639 cites W2023271753 @default.
- W2888876639 cites W2025164830 @default.
- W2888876639 cites W2030627924 @default.
- W2888876639 cites W2035700268 @default.
- W2888876639 cites W2037529553 @default.
- W2888876639 cites W2042219078 @default.
- W2888876639 cites W2052538430 @default.
- W2888876639 cites W2055950535 @default.
- W2888876639 cites W2058007525 @default.
- W2888876639 cites W2065539113 @default.
- W2888876639 cites W2068704727 @default.
- W2888876639 cites W2069231650 @default.
- W2888876639 cites W2071222585 @default.
- W2888876639 cites W2073825563 @default.
- W2888876639 cites W2074618874 @default.
- W2888876639 cites W2077613321 @default.
- W2888876639 cites W2078281924 @default.
- W2888876639 cites W2078425661 @default.
- W2888876639 cites W2078740902 @default.
- W2888876639 cites W2081017670 @default.
- W2888876639 cites W2081356769 @default.
- W2888876639 cites W2087084135 @default.
- W2888876639 cites W2090914724 @default.
- W2888876639 cites W2092826127 @default.
- W2888876639 cites W2094432971 @default.
- W2888876639 cites W2095347817 @default.
- W2888876639 cites W2099005973 @default.
- W2888876639 cites W2101313944 @default.
- W2888876639 cites W2115112615 @default.
- W2888876639 cites W2118631220 @default.
- W2888876639 cites W2122490890 @default.
- W2888876639 cites W2126625758 @default.
- W2888876639 cites W2143981217 @default.
- W2888876639 cites W2144026404 @default.
- W2888876639 cites W2148182883 @default.
- W2888876639 cites W2148284063 @default.
- W2888876639 cites W2149110469 @default.
- W2888876639 cites W2158609928 @default.
- W2888876639 cites W2168264147 @default.
- W2888876639 cites W2168467214 @default.
- W2888876639 cites W2222918417 @default.
- W2888876639 cites W2261601661 @default.
- W2888876639 cites W2299857477 @default.
- W2888876639 cites W2308493374 @default.
- W2888876639 cites W2313685026 @default.
- W2888876639 cites W2322782081 @default.
- W2888876639 cites W2325210979 @default.
- W2888876639 cites W2331937820 @default.
- W2888876639 cites W2399841482 @default.
- W2888876639 cites W2421346213 @default.
- W2888876639 cites W2442264004 @default.
- W2888876639 cites W2507406702 @default.
- W2888876639 cites W2524151452 @default.
- W2888876639 cites W2558325120 @default.
- W2888876639 cites W2581708021 @default.
- W2888876639 cites W2588998316 @default.
- W2888876639 cites W2593195341 @default.
- W2888876639 cites W2619132258 @default.
- W2888876639 cites W2619375724 @default.
- W2888876639 cites W2734555704 @default.
- W2888876639 cites W2796836628 @default.
- W2888876639 cites W2841915188 @default.
- W2888876639 cites W2886161420 @default.
- W2888876639 cites W2950907061 @default.
- W2888876639 cites W2952831323 @default.
- W2888876639 cites W4234935387 @default.
- W2888876639 doi "https://doi.org/10.1021/acs.inorgchem.8b01368" @default.
- W2888876639 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30148359" @default.
- W2888876639 hasPublicationYear "2018" @default.
- W2888876639 type Work @default.