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• W2888948829 abstract "Abstract An intramolecular Diels–Alder (IMDA) reaction efficiently accelerated by Schreiner's thiourea is reported, to build a functionalized cytochalasin scaffold (periconiasin series) for biological purposes. DFT calculation highlighted a unique multidentate cooperative hydrogen bonding in this catalysis. The deprotection end game afforded a collection of diverse structures and showed the peculiar reactivity of the Diels–Alder cycloadducts upon functionalization. Biological studies revealed strong cytotoxicity of a few compounds on breast cancer cell lines while actin polymerization is preserved." @default.
• W2888948829 created "2018-09-07" @default.
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• W2888948829 date "2018-10-21" @default.
• W2888948829 modified "2023-10-18" @default.
• W2888948829 title "Multifaceted Study on a Cytochalasin Scaffold: Lessons on Reactivity, Multidentate Catalysis, and Anticancer Properties" @default.
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• W2888948829 doi "https://doi.org/10.1002/chem.201804023" @default.
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