Matches in SemOpenAlex for { <https://semopenalex.org/work/W2889224720> ?p ?o ?g. }
- W2889224720 endingPage "812" @default.
- W2889224720 startingPage "804" @default.
- W2889224720 abstract "Abstract The kinetics and mechanism of bromination of phenol and its substituents, viz. 4‐chlorophenol, 4‐bromophenol, 4‐methylphenol, and 4‐methoxyphenol by N ‐bromophthalimide (NBP) in the presence of mercuric acetate in the temperature range of 303–318 K in aqueous acetic acid medium have been investigated. The reaction follows first‐order dependence on [NBP] and fractional order dependence of rate on [Phenol]. The activation parameters have been evaluated, and based on the observed kinetic results the probable mechanism has been proposed. Observed kinetic features and Hammett's reaction constant (ρ) suggests that bromination occurs through electrophilic substitution of bromonium ion (Br + ) into the aromatic ring in the transition state. Large negative entropy of activation values probably suggests the rigid nature of transition state." @default.
- W2889224720 created "2018-09-07" @default.
- W2889224720 creator A5013507238 @default.
- W2889224720 creator A5032624034 @default.
- W2889224720 creator A5037820765 @default.
- W2889224720 creator A5076084689 @default.
- W2889224720 date "2018-08-30" @default.
- W2889224720 modified "2023-09-27" @default.
- W2889224720 title "Synthesis, kinetics, and mechanism of bromophenols by<i>N</i>-bromophthalimide in aqueous acetic acid" @default.
- W2889224720 cites W1967028169 @default.
- W2889224720 cites W2009722239 @default.
- W2889224720 cites W2022883807 @default.
- W2889224720 cites W2027483544 @default.
- W2889224720 cites W2034663265 @default.
- W2889224720 cites W2036473503 @default.
- W2889224720 cites W2041083005 @default.
- W2889224720 cites W2075274483 @default.
- W2889224720 cites W2077134914 @default.
- W2889224720 cites W2084908076 @default.
- W2889224720 cites W2106237631 @default.
- W2889224720 cites W2109603732 @default.
- W2889224720 cites W2179333489 @default.
- W2889224720 cites W2214918685 @default.
- W2889224720 cites W2318803584 @default.
- W2889224720 cites W2515822665 @default.
- W2889224720 cites W2549712447 @default.
- W2889224720 cites W2949206821 @default.
- W2889224720 cites W2950589648 @default.
- W2889224720 cites W2952223724 @default.
- W2889224720 cites W49454964 @default.
- W2889224720 doi "https://doi.org/10.1002/kin.21214" @default.
- W2889224720 hasPublicationYear "2018" @default.
- W2889224720 type Work @default.
- W2889224720 sameAs 2889224720 @default.
- W2889224720 citedByCount "2" @default.
- W2889224720 countsByYear W28892247202020 @default.
- W2889224720 countsByYear W28892247202021 @default.
- W2889224720 crossrefType "journal-article" @default.
- W2889224720 hasAuthorship W2889224720A5013507238 @default.
- W2889224720 hasAuthorship W2889224720A5032624034 @default.
- W2889224720 hasAuthorship W2889224720A5037820765 @default.
- W2889224720 hasAuthorship W2889224720A5076084689 @default.
- W2889224720 hasConcept C121332964 @default.
- W2889224720 hasConcept C135889238 @default.
- W2889224720 hasConcept C13723534 @default.
- W2889224720 hasConcept C147597530 @default.
- W2889224720 hasConcept C148898269 @default.
- W2889224720 hasConcept C155647269 @default.
- W2889224720 hasConcept C161790260 @default.
- W2889224720 hasConcept C178790620 @default.
- W2889224720 hasConcept C184651966 @default.
- W2889224720 hasConcept C185592680 @default.
- W2889224720 hasConcept C2776673659 @default.
- W2889224720 hasConcept C2777702071 @default.
- W2889224720 hasConcept C2777965246 @default.
- W2889224720 hasConcept C50027330 @default.
- W2889224720 hasConcept C62520636 @default.
- W2889224720 hasConcept C65973085 @default.
- W2889224720 hasConcept C8503813 @default.
- W2889224720 hasConcept C89031862 @default.
- W2889224720 hasConcept C93391505 @default.
- W2889224720 hasConceptScore W2889224720C121332964 @default.
- W2889224720 hasConceptScore W2889224720C135889238 @default.
- W2889224720 hasConceptScore W2889224720C13723534 @default.
- W2889224720 hasConceptScore W2889224720C147597530 @default.
- W2889224720 hasConceptScore W2889224720C148898269 @default.
- W2889224720 hasConceptScore W2889224720C155647269 @default.
- W2889224720 hasConceptScore W2889224720C161790260 @default.
- W2889224720 hasConceptScore W2889224720C178790620 @default.
- W2889224720 hasConceptScore W2889224720C184651966 @default.
- W2889224720 hasConceptScore W2889224720C185592680 @default.
- W2889224720 hasConceptScore W2889224720C2776673659 @default.
- W2889224720 hasConceptScore W2889224720C2777702071 @default.
- W2889224720 hasConceptScore W2889224720C2777965246 @default.
- W2889224720 hasConceptScore W2889224720C50027330 @default.
- W2889224720 hasConceptScore W2889224720C62520636 @default.
- W2889224720 hasConceptScore W2889224720C65973085 @default.
- W2889224720 hasConceptScore W2889224720C8503813 @default.
- W2889224720 hasConceptScore W2889224720C89031862 @default.
- W2889224720 hasConceptScore W2889224720C93391505 @default.
- W2889224720 hasIssue "11" @default.
- W2889224720 hasLocation W28892247201 @default.
- W2889224720 hasOpenAccess W2889224720 @default.
- W2889224720 hasPrimaryLocation W28892247201 @default.
- W2889224720 hasRelatedWork W1588442473 @default.
- W2889224720 hasRelatedWork W1965141965 @default.
- W2889224720 hasRelatedWork W1996480529 @default.
- W2889224720 hasRelatedWork W2032192374 @default.
- W2889224720 hasRelatedWork W2036226750 @default.
- W2889224720 hasRelatedWork W2889224720 @default.
- W2889224720 hasRelatedWork W2951465233 @default.
- W2889224720 hasRelatedWork W2951844017 @default.
- W2889224720 hasRelatedWork W3146130210 @default.
- W2889224720 hasRelatedWork W877096456 @default.
- W2889224720 hasVolume "50" @default.
- W2889224720 isParatext "false" @default.
- W2889224720 isRetracted "false" @default.
- W2889224720 magId "2889224720" @default.