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- W2889289947 abstract "Asymmetric H-bonding catalysis as a viable strategy for enantioselective radical coupling of ketones is demonstrated. With a visible-light-mediated dual catalytic system involving a dicyanopyrazine-derived chromophore (DPZ) photosensitizer and a chiral phosphoric acid (CPA), N-aryl glycines with a variety of 1,2-diketones and isatins underwent a redox-neutral radical coupling process and furnished two series of valuable chiral 1,2-amino tertiary alcohols in high yields with good to excellent enantioselectivities (up to 97% ee). In this catalysis platform, the formation of neutral radical intermediates between ketyl and H-bonding catalyst CPA is responsible for presenting stereocontrolling factors. Its success in this work should provide inspiration for expansion to other readily accessible ketones to react with various radical species, thus leading to a productive approach to access chiral tertiary alcohol derivatives." @default.
- W2889289947 created "2018-09-07" @default.
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- W2889289947 date "2018-01-01" @default.
- W2889289947 modified "2023-10-11" @default.
- W2889289947 title "Catalytic enantioselective radical coupling of activated ketones with <i>N</i>-aryl glycines" @default.
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- W2889289947 doi "https://doi.org/10.1039/c8sc02948b" @default.
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- W2889289947 hasPublicationYear "2018" @default.
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