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• W2889358611 endingPage "3063" @default.
• W2889358611 startingPage "3055" @default.
• W2889358611 abstract "Reduction of CpMe3Ln(THF), 1-Ln (Ln = La and Gd; CpMe = C5H4Me), with KC8 in the presence of 2.2.2-cryptand (crypt) generates dark solutions, 2-Ln, with EPR spectra consistent with Ln(II) complexes: an eight-line hyperfine pattern for La at g = 1.971 and a broad single line for Gd at g = 1.988. The solutions decompose within minutes, and in the La system, a decomposition product was isolated in which a molecule of THF had been reduced by two electrons and ring-opened to generate an alkoxyalkyl-bridged bimetallic La(III) complex, [K(crypt)]2[(CpMe3La)2(μ-OCH2CH2CH2CH2)], 3-La. An analogous Pr complex, 3-Pr, was also crystallographically characterized. Since decomposition products were not readily isolated from the analogous yttrium CpMe3Y(THF)/KC8/crypt reaction, the composition of the solution of 2-Y was probed by addition of the hydrogen delivery reagent, PhSiH3, which had previously been reported to form U(III) hydrides from tris(cyclopentadienyl) U(II) complexes. This generated an Y(III) silyl complex,..." @default.
• W2889358611 created "2018-09-07" @default.
• W2889358611 creator A5011086784 @default.
• W2889358611 creator A5031307618 @default.
• W2889358611 creator A5060042756 @default.
• W2889358611 creator A5089479056 @default.
• W2889358611 date "2018-08-31" @default.
• W2889358611 modified "2023-10-03" @default.
• W2889358611 title "Reactivity of Ln(II) Complexes Supported by (C₅H₄Me)^1– Ligands with THF and PhSiH₃: Isolation of Ring-Opened, Bridging Alkoxyalkyl, Hydride, and Silyl Products" @default.
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• W2889358611 doi "https://doi.org/10.1021/acs.organomet.8b00419" @default.

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