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- W2889451631 abstract "Iron and cobalt isocyanides, Fe(CNR)5 (1) and Co2(CNR)8 (2), where R = t-butyl (tBu), adamantyl (Ad), and mesityl (Mes), were prepared by reduction of FeBr2 or CoI2 in the presence of CNR by C8K or silica-Na. These complexes were subjected to catalytic hydrosilylation of alkenes with hydrosiloxanes, and the results are compared with those obtained by previously reported Fe(OPiv)2/CNAd or Co(OPiv)2/CNAd catalyst systems. Hydrosilylation of allylic ethers with 1,1,1,3,3-pentamethyldisiloxane (PMDS) catalyzed by 1 and the reaction of several alkenes with PMDS or 1,1,1,3,5,5,5-heptamethyltrisiloxane (MD′M) catalyzed by 2 exhibited greater catalytic activity than that observed for the Fe(OPiv)2 or Co(OPiv)2/CNR catalyst system. Complexes 1 and 2 were effective for catalytic chemical modification of silicone fluids containing Si–H groups and for two-component silicone curing. In all cases, selectivity of the reaction in terms of formation of the desired product by hydrosilylation and of byproducts due to dehydr..." @default.
- W2889451631 created "2018-09-07" @default.
- W2889451631 creator A5004628028 @default.
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- W2889451631 date "2018-08-27" @default.
- W2889451631 modified "2023-10-16" @default.
- W2889451631 title "Cobalt(0) and Iron(0) Isocyanides as Catalysts for Alkene Hydrosilylation with Hydrosiloxanes" @default.
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- W2889451631 doi "https://doi.org/10.1021/acs.organomet.8b00389" @default.
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