Matches in SemOpenAlex for { <https://semopenalex.org/work/W2889520181> ?p ?o ?g. }
- W2889520181 endingPage "694" @default.
- W2889520181 startingPage "685" @default.
- W2889520181 abstract "The photobleaching dynamics of a series of three organic photovoltaic (OPV) donor polymer blends with five different fullerenes are presented. The fullerenes studied include PC60BM and four perfluoroalkylfullerenes with relatively large electron affinities, namely C60(CF3)2, C60(i-C3F7)2, C60(CF3)4, and C60(CF3)8. The donor polymers were all based on cyclopentadithiophene (CPDT) and thienopyrrolodione (TPD), but the TPD side chains were designed to include alkyl, partially fluorinated alkyl, and fluorinated phenyl groups to improve miscibility of the active layer components. Exciton harvesting was probed with photoluminescence quenching measurements. Accelerated photodegradation studies of polymer:fullerene blends were then carried out under white light illumination at ∼1.2 suns in air. A strong correlation was observed between the polymer donor photobleaching rate and the electron affinity of the fullerene. The most dramatic effect was observed for a blend of C60(CF3)8 with the donor containing fluorinated phenyl groups: the blend required 150 times the dosing of photons to bleach to 80% of its initial optical density than an analagous blend of PC60BM and non-fluorinated donor polymer. These results ultimately suggest that appropriate fluorination strategies applied to both the donor and acceptor can be a viable route toward a new paradigm of intrinsically photo- and phase-stable OPV active layers." @default.
- W2889520181 created "2018-09-07" @default.
- W2889520181 creator A5012777480 @default.
- W2889520181 creator A5017032637 @default.
- W2889520181 creator A5024675392 @default.
- W2889520181 creator A5028808065 @default.
- W2889520181 creator A5033794555 @default.
- W2889520181 creator A5039394671 @default.
- W2889520181 creator A5053363355 @default.
- W2889520181 creator A5054209248 @default.
- W2889520181 creator A5085108439 @default.
- W2889520181 creator A5086175062 @default.
- W2889520181 date "2018-11-01" @default.
- W2889520181 modified "2023-09-27" @default.
- W2889520181 title "Strategic fluorination of polymers and fullerenes improves photostability of organic photovoltaic blends" @default.
- W2889520181 cites W1545977292 @default.
- W2889520181 cites W1969325537 @default.
- W2889520181 cites W1969652545 @default.
- W2889520181 cites W1977772900 @default.
- W2889520181 cites W1981267406 @default.
- W2889520181 cites W1984625085 @default.
- W2889520181 cites W1994328499 @default.
- W2889520181 cites W2009190254 @default.
- W2889520181 cites W2018243851 @default.
- W2889520181 cites W2036454431 @default.
- W2889520181 cites W2045034489 @default.
- W2889520181 cites W2046327260 @default.
- W2889520181 cites W2048813967 @default.
- W2889520181 cites W2062880605 @default.
- W2889520181 cites W2073126198 @default.
- W2889520181 cites W2074829438 @default.
- W2889520181 cites W2090952909 @default.
- W2889520181 cites W2091210463 @default.
- W2889520181 cites W2094690008 @default.
- W2889520181 cites W2111634050 @default.
- W2889520181 cites W2113167124 @default.
- W2889520181 cites W2113261130 @default.
- W2889520181 cites W2120202887 @default.
- W2889520181 cites W2120759994 @default.
- W2889520181 cites W2123664627 @default.
- W2889520181 cites W2125325046 @default.
- W2889520181 cites W2141102859 @default.
- W2889520181 cites W2149475675 @default.
- W2889520181 cites W2277738813 @default.
- W2889520181 cites W2278284675 @default.
- W2889520181 cites W2284657883 @default.
- W2889520181 cites W2315557091 @default.
- W2889520181 cites W2319018548 @default.
- W2889520181 cites W2323587872 @default.
- W2889520181 cites W2324212695 @default.
- W2889520181 cites W2329648267 @default.
- W2889520181 cites W2335067396 @default.
- W2889520181 cites W2341477036 @default.
- W2889520181 cites W2591157920 @default.
- W2889520181 cites W2604063239 @default.
- W2889520181 cites W2609013893 @default.
- W2889520181 cites W2621579323 @default.
- W2889520181 cites W2756829020 @default.
- W2889520181 cites W2789147812 @default.
- W2889520181 cites W2803016063 @default.
- W2889520181 cites W4211012705 @default.
- W2889520181 doi "https://doi.org/10.1016/j.orgel.2018.08.045" @default.
- W2889520181 hasPublicationYear "2018" @default.
- W2889520181 type Work @default.
- W2889520181 sameAs 2889520181 @default.
- W2889520181 citedByCount "4" @default.
- W2889520181 countsByYear W28895201812019 @default.
- W2889520181 countsByYear W28895201812020 @default.
- W2889520181 countsByYear W28895201812022 @default.
- W2889520181 crossrefType "journal-article" @default.
- W2889520181 hasAuthorship W2889520181A5012777480 @default.
- W2889520181 hasAuthorship W2889520181A5017032637 @default.
- W2889520181 hasAuthorship W2889520181A5024675392 @default.
- W2889520181 hasAuthorship W2889520181A5028808065 @default.
- W2889520181 hasAuthorship W2889520181A5033794555 @default.
- W2889520181 hasAuthorship W2889520181A5039394671 @default.
- W2889520181 hasAuthorship W2889520181A5053363355 @default.
- W2889520181 hasAuthorship W2889520181A5054209248 @default.
- W2889520181 hasAuthorship W2889520181A5085108439 @default.
- W2889520181 hasAuthorship W2889520181A5086175062 @default.
- W2889520181 hasBestOaLocation W28895201811 @default.
- W2889520181 hasConcept C110884469 @default.
- W2889520181 hasConcept C120665830 @default.
- W2889520181 hasConcept C121332964 @default.
- W2889520181 hasConcept C121745418 @default.
- W2889520181 hasConcept C127413603 @default.
- W2889520181 hasConcept C15920480 @default.
- W2889520181 hasConcept C161790260 @default.
- W2889520181 hasConcept C162847780 @default.
- W2889520181 hasConcept C162862793 @default.
- W2889520181 hasConcept C178790620 @default.
- W2889520181 hasConcept C185592680 @default.
- W2889520181 hasConcept C187404810 @default.
- W2889520181 hasConcept C192562407 @default.
- W2889520181 hasConcept C2780263894 @default.
- W2889520181 hasConcept C2900893 @default.
- W2889520181 hasConcept C31332276 @default.
- W2889520181 hasConcept C42360764 @default.