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- W2889771206 endingPage "6243" @default.
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- W2889771206 abstract "A new neutral silicon-based traceless activation group (TAG) for visible-light photoredox-catalyzed hydroalkoxymethylation of alkenes is presented. This reaction involves in-situ-generated alkoxymethyl radical via single electron oxidation (SET) of α-TMS-substituted ethers, followed by subsequent conjugate addition to activated alkenes. Various functional groups were tolerated both under mild metal and metal-free conditions to provide good to excellent yields. Furthermore, the addition products were transformed to valuable synthetic building blocks, such as carboxylic acids, γ-butyrolactones, and complex aryl alkyl ethers." @default.
- W2889771206 created "2018-09-27" @default.
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- W2889771206 date "2018-09-18" @default.
- W2889771206 modified "2023-10-17" @default.
- W2889771206 title "Visible-Light Photoredox-Catalyzed Hydroalkoxymethylation of Activated Alkenes Using α-Silyl Ethers as Alkoxymethyl Radical Equivalents" @default.
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- W2889771206 doi "https://doi.org/10.1021/acs.orglett.8b02721" @default.
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