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- W2889876221 abstract "Abstract Spherical‐shape cholesteric (Ch) photonic films offer promising applications such as omnidirectional lasing and broadband reflection. Here, a strategy is reported for the fabrication of photonic Ch films by the self‐assembly of cellulose nanocrystals (CNCs) in semi‐spherical cavities. It is shown that film structure and photonic properties are controlled by the film curvature, the composition of the precursor CNC suspension, and its liquid crystalline or isotropic state. The effect of curvature of the drying Ch‐CNC films coupled with the restricted mobility of CNCs during film preparation results in the variation in pitch and helical axis inclination, thus leading to broadband reflectance properties of the films. The role of curvature of the Ch‐CNC films is underlined by comparing their distinct properties with those of planar films with the same composition. These findings provide a novel insight into the design and development of biomimetic photonic Ch films." @default.
- W2889876221 created "2018-09-27" @default.
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- W2889876221 date "2018-09-14" @default.
- W2889876221 modified "2023-10-15" @default.
- W2889876221 title "Self‐Assembly of Cellulose Nanocrystals into Semi‐Spherical Photonic Cholesteric Films" @default.
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- W2889876221 doi "https://doi.org/10.1002/adfm.201803852" @default.
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