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- W2889980738 abstract "Abstract Recent works describing the existence of an intense-blue color within the YIn1-xMnxO3 solid solution due to the presence of Mn3+ cations in trigonal-bipyramidal sites have led to the interest to prepare Al-analogues with the same 5-fold non-centrosymetric coordination. In this framework, YAlO3 structure has been recently re-examined, concluding the aluminate is indeed an oxycarbonate with the Y3Al3O8CO3 stoichiometry. In this work, we observed that pure yttrium aluminate is not only obtained for fast thermal treatments below 1000 °C but with higher Al:Y ratio than 1:1. YAl1.15(CO3)yO3+δ. The corresponding YAl1.15-xMnx(CO3)yO3+δ solid solutions were successfully prepared showing dull brown colors for the low Mn-content in comparison to Yin1-xMnxO3 series, confirming that the TBP coordination is lost in the aluminate, partly due to the presence of carbonate groups in the structure." @default.
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- W2889980738 date "2019-01-01" @default.
- W2889980738 modified "2023-09-24" @default.
- W2889980738 title "Synthesis and characterization of pure and Mn-substituted YAl1.15(CO3)yO3+δ: A variation from the classical hexagonal “YAlO3”" @default.
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- W2889980738 doi "https://doi.org/10.1016/j.jpcs.2018.09.027" @default.
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