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- W2890101186 abstract "The co-ordination compounds of inorganic ambidentate ligandshave been reviewed.The preparation and properties of several cyanate complexesof palladium(II) and platinum(II) of the types [M(NCO)4]2- and[ML2(NCO)2] are described. A criterion for the diagnosis of themode of linkage of the cyanate group based upon the integratedintensities of absorption of the C–N stretching bands has beendeveloped. The mode of linkage of the cyanate ion in thesecomplexes has been established from the positions of the infraredbands and the intensities of absorption of the C–N stretching bands.The effects of the ligands L on the bonding of the cyanate groupshave been discussed in the light of the spectral data. The coordinationbehaviours of the NCX-(X = O, S or Se)-group of ligandstowards palladium(II) and platinum(II) have been compared and arationale for their differences has been proposed in terms of thecharge differences of the N and X atoms. In all these complexes,the cyanate ion has been shown to be N-bonded. [Continues.]" @default.
- W2890101186 created "2018-09-27" @default.
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- W2890101186 date "1968-01-01" @default.
- W2890101186 modified "2023-09-26" @default.
- W2890101186 title "Co-ordination compounds of inorganic ambidentate ligands" @default.
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