Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890116901> ?p ?o ?g. }
Showing items 1 to 68 of
68
with 100 items per page.
- W2890116901 abstract "Abstract From the view point of green chemistry, CO 2 utilization technologies with solar energy including the photoredox system have been received a lot of attention. As one of them, photoredox system containing a photosensitizer and a catalyst catalyzing a reaction of a carbon–carbon bond formation from CO 2 as a feed stock were constructed. In a recent study, we reported the visible light-induced malate (C4 compound) production from pyruvate (C3 compound) and CO 2 due to carbon–carbon bond formation with the system consisting an electron donor, a photosensitizer, diphenylviologen (PV 2+ ) derivative as an electron mediator in the presence of malic enzyme (ME). However, the interaction between a photosensitizer and PV 2+ derivative has not been clarified yet. In this study, water-soluble PV 2+ derivative, 1,1′-bis( p -sulfonatophenyl)-4,4′-bipyridinium salt (PSV 2+ ) was synthesized, and its electro-, photochemical properties were evaluated. Moreover, the photoredox properties of PSV 2+ with water-soluble Zn porphyrin were studied using fluorescence spectroscopy and steady state irradiation. The fluorescence of Zn porphyrin was quenched by PSV 2+ and the two-electron reduced form of PSV 2+ were produced with Zn porphyrin with steady state irradiation. In addition, reaction solution containing triethanolamine, tetraphenylporphyrin tetrasulfonate, pyruvate, ME, Mg 2+ and PSV 2+ in CO 2 saturated bis-tris buffer (pH 7.4) was irradiated with visible light, the oxaloacetate and malate were produced. This result indicates that PSV 2+ is an efficient electron mediator in the visible light-induced redox system for carbon–carbon bond formation with ME from CO 2 as a feedstock." @default.
- W2890116901 created "2018-09-27" @default.
- W2890116901 creator A5045960919 @default.
- W2890116901 creator A5065698779 @default.
- W2890116901 creator A5084313756 @default.
- W2890116901 creator A5089918655 @default.
- W2890116901 date "2018-09-03" @default.
- W2890116901 modified "2023-10-17" @default.
- W2890116901 title "Visible light-induced reduction system of diphenylviologen derivative with water-soluble porphyrin for biocatalytic carbon–carbon bond formation from CO2" @default.
- W2890116901 cites W1964683949 @default.
- W2890116901 cites W1971169917 @default.
- W2890116901 cites W1972756007 @default.
- W2890116901 cites W1994575037 @default.
- W2890116901 cites W2041698310 @default.
- W2890116901 cites W2042492216 @default.
- W2890116901 cites W2062011962 @default.
- W2890116901 cites W2099205826 @default.
- W2890116901 cites W2120478834 @default.
- W2890116901 cites W2153922477 @default.
- W2890116901 cites W2587554666 @default.
- W2890116901 doi "https://doi.org/10.1515/pac-2018-0402" @default.
- W2890116901 hasPublicationYear "2018" @default.
- W2890116901 type Work @default.
- W2890116901 sameAs 2890116901 @default.
- W2890116901 citedByCount "3" @default.
- W2890116901 countsByYear W28901169012020 @default.
- W2890116901 countsByYear W28901169012021 @default.
- W2890116901 crossrefType "journal-article" @default.
- W2890116901 hasAuthorship W2890116901A5045960919 @default.
- W2890116901 hasAuthorship W2890116901A5065698779 @default.
- W2890116901 hasAuthorship W2890116901A5084313756 @default.
- W2890116901 hasAuthorship W2890116901A5089918655 @default.
- W2890116901 hasBestOaLocation W28901169011 @default.
- W2890116901 hasConcept C113196181 @default.
- W2890116901 hasConcept C161790260 @default.
- W2890116901 hasConcept C178790620 @default.
- W2890116901 hasConcept C185592680 @default.
- W2890116901 hasConcept C2775897365 @default.
- W2890116901 hasConcept C2778148179 @default.
- W2890116901 hasConcept C2779480358 @default.
- W2890116901 hasConcept C2781469039 @default.
- W2890116901 hasConcept C75473681 @default.
- W2890116901 hasConceptScore W2890116901C113196181 @default.
- W2890116901 hasConceptScore W2890116901C161790260 @default.
- W2890116901 hasConceptScore W2890116901C178790620 @default.
- W2890116901 hasConceptScore W2890116901C185592680 @default.
- W2890116901 hasConceptScore W2890116901C2775897365 @default.
- W2890116901 hasConceptScore W2890116901C2778148179 @default.
- W2890116901 hasConceptScore W2890116901C2779480358 @default.
- W2890116901 hasConceptScore W2890116901C2781469039 @default.
- W2890116901 hasConceptScore W2890116901C75473681 @default.
- W2890116901 hasLocation W28901169011 @default.
- W2890116901 hasOpenAccess W2890116901 @default.
- W2890116901 hasPrimaryLocation W28901169011 @default.
- W2890116901 hasRelatedWork W1963571037 @default.
- W2890116901 hasRelatedWork W2015759618 @default.
- W2890116901 hasRelatedWork W2032480314 @default.
- W2890116901 hasRelatedWork W2131236395 @default.
- W2890116901 hasRelatedWork W2290511185 @default.
- W2890116901 hasRelatedWork W2324349601 @default.
- W2890116901 hasRelatedWork W2347064894 @default.
- W2890116901 hasRelatedWork W2890116901 @default.
- W2890116901 hasRelatedWork W3149063075 @default.
- W2890116901 hasRelatedWork W4200216296 @default.
- W2890116901 isParatext "false" @default.
- W2890116901 isRetracted "false" @default.
- W2890116901 magId "2890116901" @default.
- W2890116901 workType "article" @default.