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- W2890142600 abstract "Methane is increasingly considered as a promising reductant for metal oxides, including chromite. To assess the possibilities of such reduction route, the gas-solid reactions between Ar–CH4–H2 gas mixtures and synthetic chromites are studied between 950 and 1050 °C. The influence of Mg and Al additions on the reduction-caburization of (Fe,Mg)(Cr,Al)2O4 solid solution is investigated thermodynamically, structurally and kinetically. The product phases are examined by x-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). The reaction rate is derived from real-time exhaust gas measurements and post-reaction product analyses such as oxygen analysis. Kinetic models are proposed based on the product phase morphologies and confronted with the empirical data." @default.
- W2890142600 created "2018-09-27" @default.
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- W2890142600 date "2018-01-01" @default.
- W2890142600 modified "2023-09-27" @default.
- W2890142600 title "Kinetics of Reduction-Carburization of Synthetic (Fe,Mg)(Cr,Al)2O4 Solid Solutions by Ar–CH4–H2 Gas Mixtures" @default.
- W2890142600 cites W1996039641 @default.
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- W2890142600 doi "https://doi.org/10.1007/978-3-319-95022-8_93" @default.
- W2890142600 hasPublicationYear "2018" @default.
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