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- W2890179208 abstract "The formation of 3-(2-nitrophenyl)pyruvic acid and its amide and ester derivatives – key compounds for the Reissert indole synthesis – was achieved under various reaction conditions via the acid catalyzed hydrolysis of 5-(2-nitrobenzyliden)-2,2-dimethyl-1,3-oxazolidin-4-one, which is readily available from 3-(2-nitrophenyl)oxirane-2-carboxamide. A new and highly efficient method for the synthesis of indole-2-carboxylic acid derivatives via the intramolecular reductive cyclization of o-nitrophenylpyruvic acid and its amide and ester derivatives was developed using Na2S2O4 in dioxane/water at reflux." @default.
- W2890179208 created "2018-09-27" @default.
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- W2890179208 date "2018-10-01" @default.
- W2890179208 modified "2023-10-03" @default.
- W2890179208 title "A new and efficient method for the synthesis of 3-(2-nitrophenyl)pyruvic acid derivatives and indoles based on the Reissert reaction" @default.
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- W2890179208 doi "https://doi.org/10.1016/j.tetlet.2018.09.039" @default.
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