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- W2890220925 endingPage "13041" @default.
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- W2890220925 abstract "Despite ample evidence for the unique reactivity offered by hypervalent F-iodanes, mechanistic investigations fall far behind. In order to shed light on the unusual behavior of such F-reagents, we conducted computational and experimental studies on the chemodivergent transformation of styrenes. We identified the spirocyclic F-cyclopropane as the common intermediate for both the C, H-fluorination and C, H-amination pathways. The fate of this key compound is determined by the extent of cationic charge delocalization controlled by the N-substituents. Exploiting this phenomenon, a multitude of different transformations have become available, leading, i.e., to the regiodivergent synthesis of indoles and tryptophans." @default.
- W2890220925 created "2018-09-27" @default.
- W2890220925 creator A5005449121 @default.
- W2890220925 creator A5012015505 @default.
- W2890220925 creator A5057770860 @default.
- W2890220925 creator A5084144629 @default.
- W2890220925 date "2018-09-05" @default.
- W2890220925 modified "2023-10-18" @default.
- W2890220925 title "Fluorine as a Traceless Directing Group for the Regiodivergent Synthesis of Indoles and Tryptophans" @default.
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- W2890220925 doi "https://doi.org/10.1021/jacs.8b08350" @default.
- W2890220925 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30183276" @default.
- W2890220925 hasPublicationYear "2018" @default.
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