Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890312816> ?p ?o ?g. }
- W2890312816 endingPage "894" @default.
- W2890312816 startingPage "888" @default.
- W2890312816 abstract "Pd promoted Ni supported on C60 derivative was prepared and employed to catalyze the hydrogenation of nitrobenzene (NB). The effects of the function groups of C60 derivatives and Pd on the catalytic performance of Ni-based catalyst were investigated. The characterizations illustrated that the function groups of C60 derivatives significantly affected the chemical state of Ni and Pd, which resulted in different catalytic performance. In addition, Pd as a promoter promoted the in-situ reduction of Ni under mild conditions via hydrogen spillover. Pd-Ni-N-C60, derived from C60-ethanediamine derivative with the molar ratio of Ni to Pd of 6:1, exhibited excellent catalytic performance. The high surface contents of Pd0, electron-rich Ni species and the synergistic effect between Pd, Ni and C60-ethanediamine were responsible for the outstanding catalytic performance. Under 70 °C and 1.0 MPa of H2, the nitrobenzene conversation of 98.0% and the aniline selectivity of 98.2% were obtained over Pd-6Ni-N-C60 with the reaction rate of 36.7 mol NB/(mol metal·min). The H2 pressure in the range of 0.1 MPa and 0.8 MPa obviously affected the aniline selectivity at 90 °C." @default.
- W2890312816 created "2018-09-27" @default.
- W2890312816 creator A5010511177 @default.
- W2890312816 creator A5072100773 @default.
- W2890312816 creator A5090650583 @default.
- W2890312816 date "2019-01-01" @default.
- W2890312816 modified "2023-10-06" @default.
- W2890312816 title "Hydrogenation of nitrobenzene catalyzed by Pd promoted Ni supported on C60 derivative" @default.
- W2890312816 cites W1981314240 @default.
- W2890312816 cites W1988715562 @default.
- W2890312816 cites W1991891190 @default.
- W2890312816 cites W1995610640 @default.
- W2890312816 cites W2010460388 @default.
- W2890312816 cites W2012858360 @default.
- W2890312816 cites W2037191887 @default.
- W2890312816 cites W2063895021 @default.
- W2890312816 cites W2073559422 @default.
- W2890312816 cites W2075743122 @default.
- W2890312816 cites W2100301367 @default.
- W2890312816 cites W2103056710 @default.
- W2890312816 cites W2193626626 @default.
- W2890312816 cites W2271310862 @default.
- W2890312816 cites W2303255257 @default.
- W2890312816 cites W2343070258 @default.
- W2890312816 cites W2345506369 @default.
- W2890312816 cites W2401982130 @default.
- W2890312816 cites W2404187428 @default.
- W2890312816 cites W2419365527 @default.
- W2890312816 cites W2467944406 @default.
- W2890312816 cites W2478483900 @default.
- W2890312816 cites W2485367336 @default.
- W2890312816 cites W2520785703 @default.
- W2890312816 cites W2606981299 @default.
- W2890312816 cites W2610413324 @default.
- W2890312816 cites W2756386315 @default.
- W2890312816 cites W2769820650 @default.
- W2890312816 cites W2770677889 @default.
- W2890312816 cites W3031695042 @default.
- W2890312816 cites W345346061 @default.
- W2890312816 cites W977051187 @default.
- W2890312816 doi "https://doi.org/10.1016/j.apsusc.2018.08.199" @default.
- W2890312816 hasPublicationYear "2019" @default.
- W2890312816 type Work @default.
- W2890312816 sameAs 2890312816 @default.
- W2890312816 citedByCount "21" @default.
- W2890312816 countsByYear W28903128162019 @default.
- W2890312816 countsByYear W28903128162020 @default.
- W2890312816 countsByYear W28903128162021 @default.
- W2890312816 countsByYear W28903128162022 @default.
- W2890312816 countsByYear W28903128162023 @default.
- W2890312816 crossrefType "journal-article" @default.
- W2890312816 hasAuthorship W2890312816A5010511177 @default.
- W2890312816 hasAuthorship W2890312816A5072100773 @default.
- W2890312816 hasAuthorship W2890312816A5090650583 @default.
- W2890312816 hasConcept C106159729 @default.
- W2890312816 hasConcept C111771559 @default.
- W2890312816 hasConcept C118792377 @default.
- W2890312816 hasConcept C13965031 @default.
- W2890312816 hasConcept C155647269 @default.
- W2890312816 hasConcept C161790260 @default.
- W2890312816 hasConcept C162324750 @default.
- W2890312816 hasConcept C178790620 @default.
- W2890312816 hasConcept C179104552 @default.
- W2890312816 hasConcept C185592680 @default.
- W2890312816 hasConcept C2778647224 @default.
- W2890312816 hasConcept C2779244968 @default.
- W2890312816 hasConcept C2780809723 @default.
- W2890312816 hasConcept C544153396 @default.
- W2890312816 hasConceptScore W2890312816C106159729 @default.
- W2890312816 hasConceptScore W2890312816C111771559 @default.
- W2890312816 hasConceptScore W2890312816C118792377 @default.
- W2890312816 hasConceptScore W2890312816C13965031 @default.
- W2890312816 hasConceptScore W2890312816C155647269 @default.
- W2890312816 hasConceptScore W2890312816C161790260 @default.
- W2890312816 hasConceptScore W2890312816C162324750 @default.
- W2890312816 hasConceptScore W2890312816C178790620 @default.
- W2890312816 hasConceptScore W2890312816C179104552 @default.
- W2890312816 hasConceptScore W2890312816C185592680 @default.
- W2890312816 hasConceptScore W2890312816C2778647224 @default.
- W2890312816 hasConceptScore W2890312816C2779244968 @default.
- W2890312816 hasConceptScore W2890312816C2780809723 @default.
- W2890312816 hasConceptScore W2890312816C544153396 @default.
- W2890312816 hasLocation W28903128161 @default.
- W2890312816 hasOpenAccess W2890312816 @default.
- W2890312816 hasPrimaryLocation W28903128161 @default.
- W2890312816 hasRelatedWork W1969258588 @default.
- W2890312816 hasRelatedWork W2159244846 @default.
- W2890312816 hasRelatedWork W2353852648 @default.
- W2890312816 hasRelatedWork W2370915520 @default.
- W2890312816 hasRelatedWork W2372998404 @default.
- W2890312816 hasRelatedWork W2384463919 @default.
- W2890312816 hasRelatedWork W2386355442 @default.
- W2890312816 hasRelatedWork W2515801264 @default.
- W2890312816 hasRelatedWork W2606981299 @default.
- W2890312816 hasRelatedWork W4281758031 @default.
- W2890312816 hasVolume "465" @default.
- W2890312816 isParatext "false" @default.
- W2890312816 isRetracted "false" @default.