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- W2890401128 abstract "Abstract A homoleptic zinc(II) helicate organized by a pair of achiral dipyrromethene ligands through zinc(II) coordination was synthesized to evaluate the chiroptical properties. This zinc complex showed strong exciton‐coupled chiroptical responses from the helical configuration with a large absorption dissymmetry factor | g abs | (up to 0.20). More importantly, intense polarized luminescence in the far‐red region (700–850 nm) with a fluorescence quantum yield Φ FL of 0.23 was observed for this helicate with a dissymmetry factor | g lum | of 0.022, the largest value among rare‐earth‐ and precious‐metal‐free small molecules. These unprecedentedly large g values were supported by theoretical calculations." @default.
- W2890401128 created "2018-09-27" @default.
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- W2890401128 date "2018-10-18" @default.
- W2890401128 modified "2023-09-29" @default.
- W2890401128 title "Significant Enhancement of Absorption and Luminescence Dissymmetry Factors in the Far‐Red Region: A Zinc(II) Homoleptic Helicate Formed by a Pair of Achiral Dipyrromethene Ligands" @default.
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- W2890401128 doi "https://doi.org/10.1002/chem.201804171" @default.
- W2890401128 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30179282" @default.
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