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- W2890426789 abstract "Alkaline earth metal amides (AeN''2 : Ae=Ca, Sr, Ba, N''=N(SiMe3 )2 ) catalyze alkene hydrogenation (80-120 °C, 1-6 bar H2 , 1-10 mol % cat.), with the activity increasing with metal size. Various activated C=C bonds (styrene, p-MeO-styrene, α-Me-styrene, Ph2 C=CH2 , trans-stilbene, cyclohexadiene, 1-Ph-cyclohexene), semi-activated C=C bonds (Me3 SiCH=CH2 , norbornadiene), or non-activated (isolated) C=C bonds (norbornene, 4-vinylcyclohexene, 1-hexene) could be reduced. The results show that neutral Ca or Ba catalysts are active in the challenging hydrogenation of isolated double bonds. For activated alkenes (e.g. styrene), polymerization is fully suppressed due to fast protonation of the highly reactive benzyl intermediate by N''H (formed in the catalyst initiation). Using cyclohexadiene as the H source, the first Ae metal catalyzed H-transfer hydrogenation is reported. DFT calculations on styrene hydrogenation using CaN''2 show that styrene oligomerization competes with styrene hydrogenation. Calculations also show that protonation of the benzylcalcium intermediate with N''H is a low-energy escape route, thus avoiding oligomerization." @default.
- W2890426789 created "2018-09-27" @default.
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- W2890426789 date "2018-10-15" @default.
- W2890426789 modified "2023-09-25" @default.
- W2890426789 title "Simple Alkaline‐Earth Metal Catalysts for Effective Alkene Hydrogenation" @default.
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- W2890426789 doi "https://doi.org/10.1002/anie.201810026" @default.
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