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• W2890429837 endingPage "8425" @default.
• W2890429837 startingPage "8416" @default.
• W2890429837 abstract "The gold-catalysed annulation of conjugated alkynes bearing an azido group with arenes gave annulated [c]carbazoles. Using benzene, pyrrole, and indole derivatives as the nucleophiles, benzo[c]-, pyrrolo[2,3-c]-, and indolo[2,3-c]carbazoles were produced, respectively. The reaction proceeded through pyrrole and benzene ring construction accompanied by the formation of two carbon-carbon and one carbon-nitrogen bond and the cleavage of two aromatic C-H bonds. The mechanism of the reaction with pyrrole was investigated by density functional theory calculations. N,N'-dimethylated indolo[2,3-c]carbazole showed dual ultraviolet-visible-near-infrared and fluorescence spectral changes upon electrolysis." @default.
• W2890429837 created "2018-09-27" @default.
• W2890429837 creator A5000263866 @default.
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• W2890429837 creator A5076180869 @default.
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• W2890429837 creator A5086823406 @default.
• W2890429837 creator A5090204226 @default.
• W2890429837 creator A5091711299 @default.
• W2890429837 date "2018-01-01" @default.
• W2890429837 modified "2023-10-14" @default.
• W2890429837 title "Direct synthesis of aryl-annulated [<i>c</i>]carbazoles by gold(<scp>i</scp>)-catalysed cascade reaction of azide-diynes and arenes" @default.
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