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• W2890440928 abstract "Terpyridine-attached phthalonitrile (Pn-TP) linked by cyanovinyl bond has been synthesized and employed for the preparation of subphthalocyanine (SubPc-TP) bearing conjugated terpyridine moieties. Both Pn-TP and SubPc-TP exhibited highly selective fluorescence turn-on in the presence of cyanide anions (CN−) based on chemodosimetric sensing mechanism. The conjugation of the Pn-TP molecule was interrupted by the addition of CN− at the cyanovinyl bond, showing the ratiometric fluorescence turn-on behavior. This sensing mechanism was further supported by density functional theory calculation and nuclear magnetic resonance titration studies. Optical and photophysical responses of SubPc-TP towards CN− were also investigated, in which similar fluorescence enhancement was observed due to the addition of CN− at the reactive boron trimer. The detection limit was estimated to be 94 nM, much below the World Health Organization-allowed level (1.9 μM) of CN− in water." @default.
• W2890440928 created "2018-09-27" @default.
• W2890440928 creator A5038846438 @default.
• W2890440928 creator A5071201128 @default.
• W2890440928 date "2019-01-01" @default.
• W2890440928 modified "2023-10-16" @default.
• W2890440928 title "Fluorescence turn-on chemodosimetric sensing of cyanide by cyanovinylterpyridine modified phthalonitrile and subphthalocyanine" @default.
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• W2890440928 doi "https://doi.org/10.1016/j.saa.2018.09.010" @default.
• W2890440928 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30216824" @default.
• W2890440928 hasPublicationYear "2019" @default.
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