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• W2890467925 abstract "Behavior of Ni-doped CeO2 nanorods (NR-CeNiX) in WGS reaction is evaluated. The proposed novel system simultaneously exhibits reactive (110)-ceria facets and Ni substitution. Catalytic runs for WGS reaction show greater stability, activity and selectivity towards the shift reaction regarding the traditional Ni-supported (110)-ceria system. Analysis of the surface phenomena during the catalytic reaction, followed by in-situ DRIFTS, indicates a formate via mechanism where ceria-nickel interaction plays a key role in the suppression of methane formation. Further surface characterization by X-Ray photoelectron spectroscopy evidences the existence of low-coordination Ni at the ceria surface suggesting that Ni location is the reason for the improvement attained." @default.
• W2890467925 created "2018-09-27" @default.
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• W2890467925 date "2020-06-01" @default.
• W2890467925 modified "2023-10-01" @default.
• W2890467925 title "Ni-doped ceria nanorods for the WGS reaction: Effect of Ni distribution in methane suppression" @default.
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• W2890467925 doi "https://doi.org/10.1016/j.cattod.2018.09.009" @default.
• W2890467925 hasPublicationYear "2020" @default.
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