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- W289048022 abstract "In the present work, a group of nickel-ceria nanocatalysts was synthesized by co-precipitation method and their catalytic performances were considered in CO methanation reaction. The catalysts were characterized by XRD, BET, SEM, TEM, H2-TPR, CO chemisorption and CO-TPD techniques. The results showed that addition of nickel content up to 50 wt.% increased both the CO conversion and CH4 selectivity at low temperatures while further increase in nickel content adversely affected them. The 50%Ni/CeO2 catalyst revealed an excellent activity in CO methanation due to high surface area (258 m2/g), small nickel particle size (below 5 nm) and high metal dispersion (7.31%). In CO selective methanation, CO2 conversion was completely suppressed until CO conversion reached to a maximum value, which is an important factor from commercial view point where is needed to extend operating temperature window between maximum of CO conversion and suppressing of CO2 methanation." @default.
- W289048022 created "2016-06-24" @default.
- W289048022 creator A5013242768 @default.
- W289048022 creator A5014624235 @default.
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- W289048022 date "2015-07-01" @default.
- W289048022 modified "2023-10-14" @default.
- W289048022 title "Preparation of highly active and stable NiO–CeO2 nanocatalysts for CO selective methanation" @default.
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- W289048022 doi "https://doi.org/10.1016/j.ijhydene.2015.04.127" @default.
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