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• W2890497674 startingPage "12806" @default.
• W2890497674 abstract "Rodium chiral diene complex-catalyzed enantioselective cycloaddition of aryl α-diazoarylacetates and electron-enriched Danishefsky-type dienes afforded highly functionalized and optically enriched cyclopentenones in excellent yields (up to 97% yield) and with good to excellent enantioselectivities (60–92% ee). (−)-1,13-Herbertenediol was successfully synthesized in an overall 25% yield employing the optically enriched cyclopentenone with an all-carbon quaternary center as the key intermediate." @default.
• W2890497674 created "2018-09-27" @default.
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• W2890497674 date "2018-09-14" @default.
• W2890497674 modified "2023-10-15" @default.
• W2890497674 title "Enantioselective Formal [4+1] Cycloaddition of Diazoarylacetates and the Danishefsky’s Diene: Stereoselective Synthesis of (−)-1,13-Herbertenediol" @default.
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• W2890497674 doi "https://doi.org/10.1021/acs.joc.8b01546" @default.
• W2890497674 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30215518" @default.
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