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• W2890514980 abstract "Visible-light induced perfluoroalkylation of the α-position of aldehydes via enamines was developed. The reaction proceeds by electron donor-acceptor complexation of the enamine and perfluoroalkyl iodide without any additional redox catalyst. A variety of perfluoroalkyl groups are tolerated to give various quaternary α-perfluoroalkyl aldehydes. An example using proline-derived chiral amine gives high enantioselectivity." @default.
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• W2890514980 date "2018-01-01" @default.
• W2890514980 modified "2023-10-14" @default.
• W2890514980 title "Metal-free visible-light synthesis of quaternary α-perfluoroalkyl aldehydes <i>via</i> an enamine intermediate" @default.
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• W2890514980 doi "https://doi.org/10.1039/c8ob02058b" @default.
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