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• W2890538512 endingPage "181015" @default.
• W2890538512 startingPage "181015" @default.
• W2890538512 abstract "Our trifluoromethyl functionalization method enables the dissolution and isolation of missing metallofullerenes of Gd@C74(CF3) n . After multi-stage high-performance liquid chromatography purification, Gd@C74(CF3)3 and two regioisomers of Gd@C74(CF3) are isolated. X-ray crystallographic analysis reveals that all of the isolated metallofullerenes react with CF3 groups on pentagons of the D3 h-symmetry C74 cages. Highest occupied molecular orbital-lowest unoccupied molecular orbital gaps of these trifluoromethylated derivatives, estimated by absorption spectra, are in the range 0.71-1.06 eV, consistent with density functional calculations." @default.
• W2890538512 created "2018-09-27" @default.
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• W2890538512 date "2018-09-01" @default.
• W2890538512 modified "2023-10-03" @default.
• W2890538512 title "Isolation and structure determination of missing fullerenes Gd@C ₇₄ (CF ₃ ) _<i>n</i> through <i>in situ</i> trifluoromethylation" @default.
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• W2890538512 doi "https://doi.org/10.1098/rsos.181015" @default.
• W2890538512 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6170568" @default.
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• W2890538512 hasPublicationYear "2018" @default.
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