FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890549914> ?p ?o ?g. }

• W2890549914 endingPage "163335" @default.
• W2890549914 startingPage "163335" @default.
• W2890549914 abstract "Reversible ion binding equilibria in polyelectrolyte solutions are strongly affected by interactions between dissociated ionic species. We examine how the structural correlations between ionic groups on polyelectrolytes impact the counterion binding. Treating the electrostatic correlation free energy using the classical Debye-Hückel expression leads to complete counterion dissociation in the concentrated regime. This unphysical behavior is shown to stem from improper regularization of the self-energy of dissociated ions and polyions and is mitigated by smearing point-like charges across a finite width. The influence of the self-energy on counterion binding is elaborated on by generalizing the Debye-Hückel free energy to polyelectrolytes with variable fractal dimension and stiffness. In the dilute regime, a greater propensity for binding is found for chains with more compact architectures, which in turn reduces the harsh self-repulsions of tightly packed arrangements of charge. In the concentrated regime, the effects of electrostatic correlations weaken due to screening and the extent of binding is governed by a balance of short-ranged interactions and the translational entropy of ions." @default.
• W2890549914 created "2018-09-27" @default.
• W2890549914 creator A5011646702 @default.
• W2890549914 creator A5029067826 @default.
• W2890549914 creator A5051817157 @default.
• W2890549914 creator A5071678608 @default.
• W2890549914 date "2018-10-28" @default.
• W2890549914 modified "2023-10-16" @default.
• W2890549914 title "Role of electrostatic correlations in polyelectrolyte charge association" @default.
• W2890549914 cites W1766761376 @default.
• W2890549914 cites W1912455695 @default.
• W2890549914 cites W1964100244 @default.
• W2890549914 cites W1971990401 @default.
• W2890549914 cites W1972337026 @default.
• W2890549914 cites W1974097472 @default.
• W2890549914 cites W1977546527 @default.
• W2890549914 cites W2000743830 @default.
• W2890549914 cites W2000769681 @default.
• W2890549914 cites W2002021252 @default.
• W2890549914 cites W2005638040 @default.
• W2890549914 cites W2011553134 @default.
• W2890549914 cites W2018543167 @default.
• W2890549914 cites W2022121071 @default.
• W2890549914 cites W2024815569 @default.
• W2890549914 cites W2027922717 @default.
• W2890549914 cites W2036203264 @default.
• W2890549914 cites W2038066715 @default.
• W2890549914 cites W2038581855 @default.
• W2890549914 cites W2045276792 @default.
• W2890549914 cites W2046377044 @default.
• W2890549914 cites W2047717469 @default.
• W2890549914 cites W2049664148 @default.
• W2890549914 cites W2051451527 @default.
• W2890549914 cites W2053822861 @default.
• W2890549914 cites W2061608703 @default.
• W2890549914 cites W2066139999 @default.
• W2890549914 cites W2066195845 @default.
• W2890549914 cites W2067048759 @default.
• W2890549914 cites W2067902215 @default.
• W2890549914 cites W2070129991 @default.
• W2890549914 cites W2070380156 @default.
• W2890549914 cites W2079455158 @default.
• W2890549914 cites W2085116617 @default.
• W2890549914 cites W2090227171 @default.
• W2890549914 cites W2106115249 @default.
• W2890549914 cites W2111764017 @default.
• W2890549914 cites W2112597123 @default.
• W2890549914 cites W2137630369 @default.
• W2890549914 cites W2166737817 @default.
• W2890549914 cites W2302259311 @default.
• W2890549914 cites W2302551836 @default.
• W2890549914 cites W2312232330 @default.
• W2890549914 cites W2322635315 @default.
• W2890549914 cites W2324423543 @default.
• W2890549914 cites W2324945248 @default.
• W2890549914 cites W2335336849 @default.
• W2890549914 cites W2472877839 @default.
• W2890549914 cites W2534659287 @default.
• W2890549914 cites W2548037804 @default.
• W2890549914 cites W2562137968 @default.
• W2890549914 cites W2566070701 @default.
• W2890549914 cites W2590404863 @default.
• W2890549914 cites W2595869676 @default.
• W2890549914 cites W2732832733 @default.
• W2890549914 cites W2745595887 @default.
• W2890549914 cites W2755445391 @default.
• W2890549914 cites W2767564861 @default.
• W2890549914 cites W2772283214 @default.
• W2890549914 cites W3036882637 @default.
• W2890549914 cites W3100217474 @default.
• W2890549914 cites W4211028110 @default.
• W2890549914 doi "https://doi.org/10.1063/1.5034454" @default.
• W2890549914 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30384694" @default.
• W2890549914 hasPublicationYear "2018" @default.
• W2890549914 type Work @default.
• W2890549914 sameAs 2890549914 @default.
• W2890549914 citedByCount "48" @default.
• W2890549914 countsByYear W28905499142019 @default.
• W2890549914 countsByYear W28905499142020 @default.
• W2890549914 countsByYear W28905499142021 @default.
• W2890549914 countsByYear W28905499142022 @default.
• W2890549914 countsByYear W28905499142023 @default.
• W2890549914 crossrefType "journal-article" @default.
• W2890549914 hasAuthorship W2890549914A5011646702 @default.
• W2890549914 hasAuthorship W2890549914A5029067826 @default.
• W2890549914 hasAuthorship W2890549914A5051817157 @default.
• W2890549914 hasAuthorship W2890549914A5071678608 @default.
• W2890549914 hasBestOaLocation W28905499141 @default.
• W2890549914 hasConcept C117626034 @default.
• W2890549914 hasConcept C121332964 @default.
• W2890549914 hasConcept C145148216 @default.
• W2890549914 hasConcept C147597530 @default.
• W2890549914 hasConcept C147789679 @default.
• W2890549914 hasConcept C153356533 @default.
• W2890549914 hasConcept C153864244 @default.
• W2890549914 hasConcept C159467904 @default.
• W2890549914 hasConcept C17525397 @default.
• W2890549914 hasConcept C178790620 @default.

• next