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• W2890603463 endingPage "11616" @default.
• W2890603463 startingPage "11608" @default.
• W2890603463 abstract "The dichloro titanium complexes (OSSO tBu)TiCl2 (1) and (OSSOCum)TiCl2 (2) bearing o-phenylene-bridged OSSO-type ligands [OSSO tBu-H = 6,6'-((1,2-phenylenebis(sulfanediyl))bis(methylene))bis(2,4-di-tert-butyphenol) and OSSOCum-H = 6,6'-((1,2-phenylenebis(sulfanediyl))bis(methylene))bis(2,4-bis(2-phenylpropan-2-yl)phenol)] were prepared and characterized. The X-ray structure of 1 revealed that Ti atom has an octahedral coordination geometry with an fac-fac wrapping of the [OSSO] ligand. In solution at 25 °C, 1 mainly retains the C2 symmetric structure, whereas 2 shows an equilibrium between C2- and C1-symmetric stereoisomers. Activation of 2 with (Ph3C)[B(C6F5)4] led to a highly active catalytic system with an activity of 238 kgPE·molcat-1·bar-1·h-1; linear polyethylene with a Tm of 122 °C and Mw of 107 kDa were obtained under these conditions. Catalyst 1 displayed the moderate activity of 59 kgPE·molcat-1·bar-1·h-1. Gel permeation chromatography analysis revealed the formation of high-molecular-weight polyethylenes with very large distributions of the molecular weights, indicating a low control of the polymerization process, probably becaue of the presence of different active species in solution. Density functional theory investigation provides a rational for the relative high-molecular-weight polymers obtained with these complexes. The precatalyst 2 was also active in propylene polymerization producing atactic oligomers terminated with unsaturated end groups." @default.
• W2890603463 created "2018-09-27" @default.
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• W2890603463 date "2018-09-21" @default.
• W2890603463 modified "2023-10-14" @default.
• W2890603463 title "Phenylene-Bridged OSSO-Type Titanium Complexes in the Polymerization of Ethylene and Propylene" @default.
• W2890603463 cites W1968659232 @default.
• W2890603463 cites W1968951813 @default.
• W2890603463 cites W1970233056 @default.
• W2890603463 cites W1976065021 @default.
• W2890603463 cites W1978016290 @default.
• W2890603463 cites W1978093960 @default.
• W2890603463 cites W1980353253 @default.
• W2890603463 cites W1981445895 @default.
• W2890603463 cites W1984463441 @default.
• W2890603463 cites W1985645565 @default.
• W2890603463 cites W1985870720 @default.
• W2890603463 cites W1990932567 @default.
• W2890603463 cites W1992466397 @default.
• W2890603463 cites W1993846049 @default.
• W2890603463 cites W1994904151 @default.
• W2890603463 cites W2002788226 @default.
• W2890603463 cites W2003243020 @default.
• W2890603463 cites W2007075324 @default.
• W2890603463 cites W2008964226 @default.
• W2890603463 cites W2009662589 @default.
• W2890603463 cites W2012985164 @default.
• W2890603463 cites W2016813855 @default.
• W2890603463 cites W2019634464 @default.
• W2890603463 cites W2021152241 @default.
• W2890603463 cites W2021389295 @default.
• W2890603463 cites W2022453244 @default.
• W2890603463 cites W2024159607 @default.
• W2890603463 cites W2030258959 @default.
• W2890603463 cites W2030687437 @default.
• W2890603463 cites W2035343844 @default.
• W2890603463 cites W2037630208 @default.
• W2890603463 cites W2043194258 @default.
• W2890603463 cites W2044268473 @default.
• W2890603463 cites W2047728428 @default.
• W2890603463 cites W2052648804 @default.
• W2890603463 cites W2053621585 @default.
• W2890603463 cites W2054109569 @default.
• W2890603463 cites W2057699290 @default.
• W2890603463 cites W2062666119 @default.
• W2890603463 cites W2067520304 @default.
• W2890603463 cites W2068617439 @default.
• W2890603463 cites W2070418435 @default.
• W2890603463 cites W2070851671 @default.
• W2890603463 cites W2074962342 @default.
• W2890603463 cites W2078146328 @default.
• W2890603463 cites W2078830522 @default.
• W2890603463 cites W2079463138 @default.
• W2890603463 cites W2086957099 @default.
• W2890603463 cites W2089947109 @default.
• W2890603463 cites W2090262633 @default.
• W2890603463 cites W2092928008 @default.
• W2890603463 cites W2094355707 @default.
• W2890603463 cites W2094783956 @default.
• W2890603463 cites W2102684272 @default.
• W2890603463 cites W2112636684 @default.
• W2890603463 cites W2117174198 @default.
• W2890603463 cites W2124709351 @default.
• W2890603463 cites W2139585762 @default.
• W2890603463 cites W2142003905 @default.
• W2890603463 cites W2146335496 @default.
• W2890603463 cites W2149295256 @default.
• W2890603463 cites W2150184367 @default.
• W2890603463 cites W2161065948 @default.
• W2890603463 cites W2318496742 @default.
• W2890603463 cites W2326548683 @default.
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• W2890603463 cites W2332945486 @default.
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• W2890603463 cites W3036723969 @default.
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• W2890603463 doi "https://doi.org/10.1021/acsomega.8b01550" @default.
• W2890603463 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6645219" @default.
• W2890603463 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/31459259" @default.
• W2890603463 hasPublicationYear "2018" @default.
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