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- W2890636082 abstract "Four new liquid crystal cyclic carbonate monomers M1–M4, with cholesteryl moiety and flexible spacer of different lengths, were synthesised through coupling reaction. The chemical structures, mesophase properties and thermal behaviour of the monomers were characterised with Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy (1H NMR), polarising optical microscopy, differential scanning calorimetry and X-ray diffraction. Based on these results, the relationship between the number of methylene groups into flexible chain and the mesomorphism of the monomers was investigated. It was found that all the monomers showed a focal conic texture of a smectic A phase and exhibited an interdigitated molecular arrangement. Moreover, the glass transition temperature and the isotropisation temperature of the monomers except M1 decreased, and the mesophase range narrowed as the number of methylene units into the flexible chain increased." @default.
- W2890636082 created "2018-09-27" @default.
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- W2890636082 date "2018-09-12" @default.
- W2890636082 modified "2023-10-01" @default.
- W2890636082 title "Synthesis and liquid crystal properties of new cyclic carbonate monomers functionalised with cholesteryl moiety" @default.
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- W2890636082 doi "https://doi.org/10.1080/02678292.2018.1499974" @default.
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