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• W2890714645 abstract "The particular nature of tetrahydropyrido[4,3-e]-1,4,2-dioxazines of type 1 allows the regio- and stereoselective obtainment of substituted N-carbamoyl tetrahydropyridines by common reducing agents. A completely novel, biologically active, bicyclic 1,3-diaza-4-oxa-[3.3.1]-nonene scaffold can be generated by the use of lithium triethylborohydride through unprecedented cascade syn-SN2′ reduction/carbamate reduction/cyclization reactions. The remarkable regioselectivity switches in the allylic reduction process have been rationalized with the aid of computational studies." @default.
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• W2890714645 date "2018-09-13" @default.
• W2890714645 modified "2023-09-25" @default.
• W2890714645 title "Regio- and Stereodivergent Allylic Reductions of Bicyclic Piperidine Enecarbamate Derivatives" @default.
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• W2890714645 doi "https://doi.org/10.1021/acs.joc.8b01601" @default.
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