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• W2890729638 abstract "A dramatic N-substituent controlled tandem annulation of 2-(2-(2-bromoethyl)phenyl)-1-sulfonylaziridines with 1,3-dicarbonyl compounds has been developed. When the N-substituent was a 4-methylbenzenesulfonyl group (Ts), sequential ring opening of aziridines, nucleophilic substitution, and lactamization took place to provide a series of hexahydrobenz[e]isoindole compounds in good yields with good diastereoselectivities. By contrast, 3-benzazepine compounds were afforded in good yields via ring opening of aziridines and nucleophilic substitution when the N-substituent was the 4-nitrobenzenesulfonyl group (Ns)." @default.
• W2890729638 created "2018-09-27" @default.
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• W2890729638 date "2018-09-06" @default.
• W2890729638 modified "2023-10-14" @default.
• W2890729638 title "Substitution-Controlled Selective Formation of Hexahydrobenz[<i>e</i>]isoindoles and 3-Benzazepines via In(OTf)₃-Catalyzed Tandem Annulations" @default.
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• W2890729638 doi "https://doi.org/10.1021/acs.orglett.8b02406" @default.
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