Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890735579> ?p ?o ?g. }
- W2890735579 endingPage "5972" @default.
- W2890735579 startingPage "5969" @default.
- W2890735579 abstract "A carbene-catalyzed enantioselective addition of enals to five-membered cyclic imines is developed. The reaction gives chiral quaternary α-amino phosphonates bearing tetrasubstituted carbon centers with excellent enantioselectivities. The imine substrates can be generated in situ from the corresponding amines under an oxidative condition that is compatible with the carbene catalysis. Thus, a one-pot cross-dehydrogenative-coupling (CDC) reaction between enals and amines is also realized with high enantioselectivity remaining. The method provides quick enantioselective access to amino phosphonates with potential applications in medicines and pesticides." @default.
- W2890735579 created "2018-09-27" @default.
- W2890735579 creator A5006877870 @default.
- W2890735579 creator A5010310776 @default.
- W2890735579 creator A5052933299 @default.
- W2890735579 creator A5053340108 @default.
- W2890735579 creator A5056403313 @default.
- W2890735579 creator A5089109311 @default.
- W2890735579 date "2018-09-13" @default.
- W2890735579 modified "2023-10-16" @default.
- W2890735579 title "Carbene-Catalyzed [4 + 2] Cycloadditions of Vinyl Enolate and (in Situ Generated) Imines for Enantioselective Synthesis of Quaternary α-Amino Phosphonates" @default.
- W2890735579 cites W1516820656 @default.
- W2890735579 cites W1714804572 @default.
- W2890735579 cites W1966757833 @default.
- W2890735579 cites W1968562678 @default.
- W2890735579 cites W1981133365 @default.
- W2890735579 cites W1982558875 @default.
- W2890735579 cites W1982951699 @default.
- W2890735579 cites W1987086964 @default.
- W2890735579 cites W1991854741 @default.
- W2890735579 cites W1993145131 @default.
- W2890735579 cites W1994631366 @default.
- W2890735579 cites W1994899761 @default.
- W2890735579 cites W1997217559 @default.
- W2890735579 cites W1999136181 @default.
- W2890735579 cites W2005515540 @default.
- W2890735579 cites W2011161714 @default.
- W2890735579 cites W2019115597 @default.
- W2890735579 cites W2021202994 @default.
- W2890735579 cites W2034764833 @default.
- W2890735579 cites W2035817679 @default.
- W2890735579 cites W2041441646 @default.
- W2890735579 cites W2045832236 @default.
- W2890735579 cites W2047100973 @default.
- W2890735579 cites W2055268992 @default.
- W2890735579 cites W2056804288 @default.
- W2890735579 cites W2070096324 @default.
- W2890735579 cites W2074952873 @default.
- W2890735579 cites W2077596354 @default.
- W2890735579 cites W2087568947 @default.
- W2890735579 cites W2092088133 @default.
- W2890735579 cites W2095621360 @default.
- W2890735579 cites W2114740869 @default.
- W2890735579 cites W2126458549 @default.
- W2890735579 cites W2153045427 @default.
- W2890735579 cites W2155422063 @default.
- W2890735579 cites W2160293685 @default.
- W2890735579 cites W2265865093 @default.
- W2890735579 cites W2316222080 @default.
- W2890735579 cites W2318066473 @default.
- W2890735579 cites W2329076747 @default.
- W2890735579 cites W2336153237 @default.
- W2890735579 cites W2483412702 @default.
- W2890735579 cites W2759961168 @default.
- W2890735579 cites W2801097499 @default.
- W2890735579 cites W2950995577 @default.
- W2890735579 cites W2951304418 @default.
- W2890735579 cites W2953279353 @default.
- W2890735579 doi "https://doi.org/10.1021/acs.orglett.8b02707" @default.
- W2890735579 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/30211562" @default.
- W2890735579 hasPublicationYear "2018" @default.
- W2890735579 type Work @default.
- W2890735579 sameAs 2890735579 @default.
- W2890735579 citedByCount "16" @default.
- W2890735579 countsByYear W28907355792019 @default.
- W2890735579 countsByYear W28907355792020 @default.
- W2890735579 countsByYear W28907355792021 @default.
- W2890735579 countsByYear W28907355792022 @default.
- W2890735579 countsByYear W28907355792023 @default.
- W2890735579 crossrefType "journal-article" @default.
- W2890735579 hasAuthorship W2890735579A5006877870 @default.
- W2890735579 hasAuthorship W2890735579A5010310776 @default.
- W2890735579 hasAuthorship W2890735579A5052933299 @default.
- W2890735579 hasAuthorship W2890735579A5053340108 @default.
- W2890735579 hasAuthorship W2890735579A5056403313 @default.
- W2890735579 hasAuthorship W2890735579A5089109311 @default.
- W2890735579 hasBestOaLocation W28907355792 @default.
- W2890735579 hasConcept C146686406 @default.
- W2890735579 hasConcept C155647269 @default.
- W2890735579 hasConcept C161790260 @default.
- W2890735579 hasConcept C178790620 @default.
- W2890735579 hasConcept C185592680 @default.
- W2890735579 hasConcept C21951064 @default.
- W2890735579 hasConcept C2776573223 @default.
- W2890735579 hasConcept C2777164566 @default.
- W2890735579 hasConcept C2777822432 @default.
- W2890735579 hasConcept C2994484720 @default.
- W2890735579 hasConcept C66972969 @default.
- W2890735579 hasConceptScore W2890735579C146686406 @default.
- W2890735579 hasConceptScore W2890735579C155647269 @default.
- W2890735579 hasConceptScore W2890735579C161790260 @default.
- W2890735579 hasConceptScore W2890735579C178790620 @default.
- W2890735579 hasConceptScore W2890735579C185592680 @default.
- W2890735579 hasConceptScore W2890735579C21951064 @default.
- W2890735579 hasConceptScore W2890735579C2776573223 @default.
- W2890735579 hasConceptScore W2890735579C2777164566 @default.
- W2890735579 hasConceptScore W2890735579C2777822432 @default.
- W2890735579 hasConceptScore W2890735579C2994484720 @default.