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- W2890766171 abstract "Tri‐substituted cyclopentadienes and cyclopentanes, high‐value‐added compounds, are readily prepared from ethyl levulinate, a chemical platform easily obtained from biomass. Key steps involve coupling two molecules of ethyl levulinate in the presence of pyrrolidine, followed by a base‐catalyzed intramolecular aldol condensation, to provide a singly‐purified and easily derivatizable cyclopentadiene in almost 40 % isolated overall yield. Reaction conditions are mild, simple and employ green solvents such as ethanol and anisole. This method opens a new pathway to preparing complex molecules from renewable feedstocks." @default.
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- W2890766171 date "2018-11-09" @default.
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- W2890766171 title "Direct Synthesis of Highly Substituted Cyclopentadienes and Derivatives from the Self-Condensation of Renewable Ethyl Levulinate" @default.
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- W2890766171 doi "https://doi.org/10.1002/ejoc.201801197" @default.
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