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- W2890778478 abstract "In this study, as spun porous polyacrylonitrile (PAN) micro/nanofiber membranes were produced by electrospinning a ternary system of PAN/N, N‑dimethylformamide (DMF)/water. The initiation of interconnected porous structure was due to the spinodal phase separation that happened during the electrospinning. In a further step, non-porous PAN micro/nanofiber membranes were prepared with a similar diameter. Afterward, these membranes were utilized as Li-ion battery (LIB) separators. The impacts of membrane porosity on physical, mechanical and electrochemical properties of the porous PAN micro/nanofiber membranes have been discovered and compared with the non-porous PAN micro/nanofiber membranes and the commercial celgard polypropelene (Celgard PP) separators. The Brunauer–Emmett–Teller (BET) specific surface area of porous PAN micro/nanofiber membrane was 52.6 m2 g−1. This was 3 times higher than that of non-porous PAN micro/nanofiber membrane under the same conditions. The air permeability value of the porous PAN micro/nanofiber membrane was higher than the non-porous PAN micro/nanofiber membrane and the commercial Celgard PP separator because of higher porosity (83%). The results indicated that the electrolyte-soaked porous PAN micro/nanofiber membrane had greatest ionic conductivity due to considerable porosity and high electrolyte uptake. Also Li(Ni1/3Co1/3Mn1/3)o2 (NCM)/separator/Li metal half-cell with porous PAN micro/nanofiber membrane had higher discharge capacity than the other cells (130 mAhg−1 at C/10 rate)." @default.
- W2890778478 created "2018-09-27" @default.
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- W2890778478 date "2018-11-01" @default.
- W2890778478 modified "2023-10-06" @default.
- W2890778478 title "Porous PAN micro/nanofiber separators for enhanced lithium-ion battery performance" @default.
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- W2890778478 doi "https://doi.org/10.1016/j.ssi.2018.08.013" @default.
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