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- W2890791357 abstract "Abstract We designed and synthesized a dibenzothiphene dioxide‐based homopolysiloxane, PDBTSi, and a carbazole‐dibenzothiophene dioxide alternating copolysiloxane, PCzSi‐ alt ‐PDBTSi, respectively. Both PDBTSi and PCzSi‐ alt ‐PDBTSi possess an improved solubility, good film‐forming ability and extremely high thermal stability due to introduction of polysiloxane main chains. Meanwhile, PDBTSi and PCzSi‐ alt ‐PDBTSi exhibit high triplet energy levels of 2.95 eV and 3.05 eV, respectively. Furthermore, PDBTSi possesses good electron‐transporting property with an electron mobility of 1.02×10 −4 cm 2 V −1 s −1 and a relatively balanced hole mobility of 8.76×10 −5 cm 2 V −1 s −1 . In contrast, PCzSi‐ alt ‐PDBTSi exhibits an electron mobility of 4.65×10 −5 cm 2 V −1 s −1 and a hole mobility of 1.17×10 −4 cm 2 V −1 s −1 . Therefore, our results here provide a feasible strategy to obtain solution‐processed polysiloxane materials with high and balanced electron‐ and hole‐transporting properties." @default.
- W2890791357 created "2018-09-27" @default.
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- W2890791357 date "2018-10-09" @default.
- W2890791357 modified "2023-10-14" @default.
- W2890791357 title "Synthesis and Charge-Transporting Properties of Dibenzothiphene Dioxide-Based Polysiloxanes" @default.
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- W2890791357 doi "https://doi.org/10.1002/asia.201801099" @default.
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