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- W2890817174 abstract "An efficient and highly regioselective Bi III catalyzed alcoholysis and Hydrochlorination reaction of spiro‐epoxy oxindole is demonstrated with alcohols and chlorine for easy access to 3,3‐disubstituted oxindoles. This protocol furnished alkyloxy and chlorinated products at the C3 spiro center of the epoxy ring in high yields up to 98 % with excellent regioselectivity > 99 %. The synthetic protocol was further exploited for the synthesis of the anti‐cancer active molecule, 1‐benzyl‐3‐(hydroxymethyl)‐3‐(phenylamino)indolin‐2‐one." @default.
- W2890817174 created "2018-09-27" @default.
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- W2890817174 date "2018-10-24" @default.
- W2890817174 modified "2023-10-02" @default.
- W2890817174 title "Regioselective Alcoholysis and Hydrochlorination Reactions of Spiro-Epoxy Oxindoles at the Spiro-Centre: Synthesis of 3,3-Disubstituted Oxindoles and Application for Anticancer Agents" @default.
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- W2890817174 doi "https://doi.org/10.1002/ejoc.201801002" @default.
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