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- W2890829315 abstract "Abstract The beneficial effects of Sn(IV) as a dopant in ultrathin hematite (α‐Fe 2 O 3 ) photoanodes for water oxidation are examined. Different Sn concentration profiles are prepared by alternating atomic layer deposition of Fe 2 O 3 and SnO x . Combined data from spectrophotometry and intensity‐modulated photocurrent spectroscopy yields the individual process efficiencies for light harvesting, charge separation, and charge transfer. The best performing photoanodes are Sn‐doped both on the surface and in the subsurface region and benefit from enhanced charge separation and transfer. Sn‐doping throughout the bulk of the hematite photoanode causes segregation at the grain boundaries and hence a lower overall efficiency. Fe 2 O 3 (0001) and terminations, shown to be dominant by microstructural analysis, are investigated by density functional theory (DFT) calculations. The energetics of surface intermediates during the oxygen evolution reaction (OER) reveal that while Sn‐doping decreases the overpotential on the (0001) surface, the Fe 2 O 3 orientation shows one of the lowest overpotentials reported for hematite so far. Electronic structure calculations demonstrate that Sn‐doping on the surface also enhances the charge transfer efficiency by elimination of surface hole trap states (passivation) and that subsurface Sn‐doping introduces a gradient of the band edges that reinforces the band bending at the semiconductor/electrolyte interface and thus boosts charge separation." @default.
- W2890829315 created "2018-09-27" @default.
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- W2890829315 date "2018-09-19" @default.
- W2890829315 modified "2023-10-16" @default.
- W2890829315 title "Why Tin-Doping Enhances the Efficiency of Hematite Photoanodes for Water Splitting-The Full Picture" @default.
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- W2890829315 doi "https://doi.org/10.1002/adfm.201804472" @default.
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