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• W2890832593 startingPage "40" @default.
• W2890832593 abstract "On the basis of dynamic interfacial tension measurements, Ca2+ has been shown specifically to interact with naphthenic acid (NA) at the n-heptane/water interface, consistent with NA adsorption followed by interfacial complexation and formation of a more ordered interfacial film. Optimum concentrations of Ca2+ and NA have been found to yield lower, time-dependent interfacial tensions, not evident for Mg2+ and Sr2+ or for several alkali metal ions studied. The results reflect the specific hydration and coordination chemistry of Ca2+ seen in biology. Owing to the ubiquitous presence of Ca2+ in oilfield waters, this finding has potential relevance to the surface chemistry underlying crude oil recovery. For example, “locking” acidic components at water/oil interfaces may be important for crude oil emulsion stability, or in bonding bulk oil to mineral surfaces through an aqueous phase, potentially relevant for carbonate reservoirs. The relevance of the present results to low salinity waterflooding as an enhanced crude oil recovery technique is also discussed." @default.
• W2890832593 created "2018-09-27" @default.
• W2890832593 creator A5039473351 @default.
• W2890832593 creator A5042351803 @default.
• W2890832593 date "2018-09-18" @default.
• W2890832593 modified "2023-10-16" @default.
• W2890832593 title "Metal Ion Interactions with Crude Oil Components: Specificity of Ca2+ Binding to Naphthenic Acid at an Oil/Water Interface" @default.
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