Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890833518> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2890833518 abstract "Atoms in Molecules (AIM), Natural Bond Orbital (NBO), and normal coordinate analysis have been carried out at the global minimum structures of TH5+ (T = C/Si/Ge). All these analyses lead to a consistent structure for these three protonated TH4 molecules. The CH5+ has a structure with three short and two long C-H covalent bonds and no H-H bond. Hence, the popular characterization of protonated methane as a weakly bound CH3+ and H2 is inconsistent with these results. However, SiH5+ and GeH5+ are both indeed a complex formed between TH3+ and H2 stabilized by a tetrel bond, with the H2 being the tetrel bond acceptor. The three-center-two-electron bond (3c-2e) in CH5+ has an open structure, which can be characterized as a V-type 3c-2e bond and that found in SiH5+ and GeH5+ is a T-type 3c-2e bond. This difference could be understood based on the typical C-H, Si-H, Ge-H and H-H bond energies. Moreover, this structural difference observed in TH5+ can explain the trend in proton affinity of TH4. Carbon is selective in forming a ‘tetrel bond’ and when it does, it might be worthwhile to highlight it as a ‘carbon bond’." @default.
- W2890833518 created "2018-09-27" @default.
- W2890833518 creator A5027524594 @default.
- W2890833518 creator A5031630805 @default.
- W2890833518 date "2018-09-13" @default.
- W2890833518 modified "2023-09-27" @default.
- W2890833518 title "Inter/Intramolecular Bonds in TH<sub>5</sub><sup>+</sup> (T = C/Si/Ge): The Uniqueness of Carbon Bonds in Tetrel Bonds" @default.
- W2890833518 cites W1587986719 @default.
- W2890833518 cites W1597773817 @default.
- W2890833518 cites W1613363476 @default.
- W2890833518 cites W1964467032 @default.
- W2890833518 cites W1969169061 @default.
- W2890833518 cites W1987036024 @default.
- W2890833518 cites W1990502351 @default.
- W2890833518 cites W1997460427 @default.
- W2890833518 cites W2003470585 @default.
- W2890833518 cites W2015674670 @default.
- W2890833518 cites W2016485433 @default.
- W2890833518 cites W2020357252 @default.
- W2890833518 cites W2023584194 @default.
- W2890833518 cites W2026394340 @default.
- W2890833518 cites W2031409974 @default.
- W2890833518 cites W2034832203 @default.
- W2890833518 cites W2042832353 @default.
- W2890833518 cites W2045700706 @default.
- W2890833518 cites W2045971000 @default.
- W2890833518 cites W2066363676 @default.
- W2890833518 cites W2067895272 @default.
- W2890833518 cites W2071248899 @default.
- W2890833518 cites W2073913090 @default.
- W2890833518 cites W2076317072 @default.
- W2890833518 cites W2078342093 @default.
- W2890833518 cites W2094827639 @default.
- W2890833518 cites W2116672419 @default.
- W2890833518 cites W2117628002 @default.
- W2890833518 cites W2323633833 @default.
- W2890833518 cites W2401267289 @default.
- W2890833518 cites W626697813 @default.
- W2890833518 doi "https://doi.org/10.20944/preprints201809.0228.v1" @default.
- W2890833518 hasPublicationYear "2018" @default.
- W2890833518 type Work @default.
- W2890833518 sameAs 2890833518 @default.
- W2890833518 citedByCount "1" @default.
- W2890833518 countsByYear W28908335182023 @default.
- W2890833518 crossrefType "posted-content" @default.
- W2890833518 hasAuthorship W2890833518A5027524594 @default.
- W2890833518 hasAuthorship W2890833518A5031630805 @default.
- W2890833518 hasBestOaLocation W28908335181 @default.
- W2890833518 hasConcept C108797602 @default.
- W2890833518 hasConcept C112887158 @default.
- W2890833518 hasConcept C130188946 @default.
- W2890833518 hasConcept C145148216 @default.
- W2890833518 hasConcept C178790620 @default.
- W2890833518 hasConcept C180577832 @default.
- W2890833518 hasConcept C185592680 @default.
- W2890833518 hasConcept C2781311116 @default.
- W2890833518 hasConcept C30095370 @default.
- W2890833518 hasConcept C32909587 @default.
- W2890833518 hasConcept C63385615 @default.
- W2890833518 hasConcept C71240020 @default.
- W2890833518 hasConcept C75079739 @default.
- W2890833518 hasConcept C8010536 @default.
- W2890833518 hasConceptScore W2890833518C108797602 @default.
- W2890833518 hasConceptScore W2890833518C112887158 @default.
- W2890833518 hasConceptScore W2890833518C130188946 @default.
- W2890833518 hasConceptScore W2890833518C145148216 @default.
- W2890833518 hasConceptScore W2890833518C178790620 @default.
- W2890833518 hasConceptScore W2890833518C180577832 @default.
- W2890833518 hasConceptScore W2890833518C185592680 @default.
- W2890833518 hasConceptScore W2890833518C2781311116 @default.
- W2890833518 hasConceptScore W2890833518C30095370 @default.
- W2890833518 hasConceptScore W2890833518C32909587 @default.
- W2890833518 hasConceptScore W2890833518C63385615 @default.
- W2890833518 hasConceptScore W2890833518C71240020 @default.
- W2890833518 hasConceptScore W2890833518C75079739 @default.
- W2890833518 hasConceptScore W2890833518C8010536 @default.
- W2890833518 hasLocation W28908335181 @default.
- W2890833518 hasOpenAccess W2890833518 @default.
- W2890833518 hasPrimaryLocation W28908335181 @default.
- W2890833518 hasRelatedWork W1983232232 @default.
- W2890833518 hasRelatedWork W1992333308 @default.
- W2890833518 hasRelatedWork W2006252551 @default.
- W2890833518 hasRelatedWork W2029790788 @default.
- W2890833518 hasRelatedWork W2335350754 @default.
- W2890833518 hasRelatedWork W2500179633 @default.
- W2890833518 hasRelatedWork W2766052992 @default.
- W2890833518 hasRelatedWork W2909989786 @default.
- W2890833518 hasRelatedWork W2979632710 @default.
- W2890833518 hasRelatedWork W3196588449 @default.
- W2890833518 isParatext "false" @default.
- W2890833518 isRetracted "false" @default.
- W2890833518 magId "2890833518" @default.
- W2890833518 workType "article" @default.