Matches in SemOpenAlex for { <https://semopenalex.org/work/W2890852441> ?p ?o ?g. }
- W2890852441 endingPage "3297" @default.
- W2890852441 startingPage "3286" @default.
- W2890852441 abstract "A series of six pincer–ruthenium complexes has been synthesized and applied in the catalytic hydrogenation of esters. The ruthenium complexes have the formula Ru(pincer)HCl(CO), where the CNN-pincer ligands feature N-heterocyclic carbene (NHC), pyridine, and dialkylamino donor groups. Through systematic variation of the steric bulk of the NHC substituent and the amine substituents, a clear structure–function relationship emerges. The most active catalysts in this series feature the bulkiest NHC substituent employed, 2,6-diisopropylphenyl. For the dialkylamino group, catalysts substituted with isopropyl or ethyl groups were the most active, while catalysts substituted with methyl groups were significantly less active. The most active catalyst discovered catalyzes the complete hydrogenation of a range of esters at loadings of 0.05–0.2 mol %." @default.
- W2890852441 created "2018-09-27" @default.
- W2890852441 creator A5013154659 @default.
- W2890852441 creator A5021337428 @default.
- W2890852441 creator A5033847023 @default.
- W2890852441 creator A5039669028 @default.
- W2890852441 creator A5040434073 @default.
- W2890852441 creator A5046548334 @default.
- W2890852441 creator A5048314589 @default.
- W2890852441 creator A5056087428 @default.
- W2890852441 creator A5059366665 @default.
- W2890852441 creator A5067689496 @default.
- W2890852441 date "2018-09-17" @default.
- W2890852441 modified "2023-09-24" @default.
- W2890852441 title "Structure–Function Relationship in Ester Hydrogenation Catalyzed by Ruthenium CNN-Pincer Complexes" @default.
- W2890852441 cites W1592981712 @default.
- W2890852441 cites W1823874480 @default.
- W2890852441 cites W1847832255 @default.
- W2890852441 cites W1850447797 @default.
- W2890852441 cites W1928761229 @default.
- W2890852441 cites W1979368458 @default.
- W2890852441 cites W1981848964 @default.
- W2890852441 cites W1982100202 @default.
- W2890852441 cites W1983107490 @default.
- W2890852441 cites W1985399221 @default.
- W2890852441 cites W1985418093 @default.
- W2890852441 cites W1988373156 @default.
- W2890852441 cites W1993189522 @default.
- W2890852441 cites W1996123855 @default.
- W2890852441 cites W2005227604 @default.
- W2890852441 cites W2009626516 @default.
- W2890852441 cites W2018215217 @default.
- W2890852441 cites W2018627975 @default.
- W2890852441 cites W2027324268 @default.
- W2890852441 cites W2030125641 @default.
- W2890852441 cites W2033430056 @default.
- W2890852441 cites W2033618313 @default.
- W2890852441 cites W2036572907 @default.
- W2890852441 cites W2045572952 @default.
- W2890852441 cites W2048503721 @default.
- W2890852441 cites W2050592102 @default.
- W2890852441 cites W2050979151 @default.
- W2890852441 cites W2053022836 @default.
- W2890852441 cites W2059420460 @default.
- W2890852441 cites W2060852195 @default.
- W2890852441 cites W2061382464 @default.
- W2890852441 cites W2065386992 @default.
- W2890852441 cites W2068446696 @default.
- W2890852441 cites W2070058538 @default.
- W2890852441 cites W2073036519 @default.
- W2890852441 cites W2098007573 @default.
- W2890852441 cites W2098697963 @default.
- W2890852441 cites W2105835420 @default.
- W2890852441 cites W2107400648 @default.
- W2890852441 cites W2113348154 @default.
- W2890852441 cites W2114216497 @default.
- W2890852441 cites W2120968379 @default.
- W2890852441 cites W2121097425 @default.
- W2890852441 cites W2133978452 @default.
- W2890852441 cites W2144528488 @default.
- W2890852441 cites W2148138360 @default.
- W2890852441 cites W2153422107 @default.
- W2890852441 cites W2155539636 @default.
- W2890852441 cites W2165005699 @default.
- W2890852441 cites W2166449173 @default.
- W2890852441 cites W2168029425 @default.
- W2890852441 cites W2211824843 @default.
- W2890852441 cites W2270992526 @default.
- W2890852441 cites W2314923722 @default.
- W2890852441 cites W2318218875 @default.
- W2890852441 cites W2318689383 @default.
- W2890852441 cites W2319671162 @default.
- W2890852441 cites W2320108646 @default.
- W2890852441 cites W2320601170 @default.
- W2890852441 cites W2321987880 @default.
- W2890852441 cites W2323900808 @default.
- W2890852441 cites W2327481815 @default.
- W2890852441 cites W2328340519 @default.
- W2890852441 cites W2328495966 @default.
- W2890852441 cites W2329553987 @default.
- W2890852441 cites W2330838277 @default.
- W2890852441 cites W2331268998 @default.
- W2890852441 cites W2331809099 @default.
- W2890852441 cites W2332217703 @default.
- W2890852441 cites W2336860317 @default.
- W2890852441 cites W2339650607 @default.
- W2890852441 cites W2343767939 @default.
- W2890852441 cites W2344003166 @default.
- W2890852441 cites W2345934912 @default.
- W2890852441 cites W2396763046 @default.
- W2890852441 cites W2464647111 @default.
- W2890852441 cites W2484675495 @default.
- W2890852441 cites W2510357970 @default.
- W2890852441 cites W2517674802 @default.
- W2890852441 cites W2535816085 @default.
- W2890852441 cites W2548856390 @default.
- W2890852441 cites W2554848284 @default.
- W2890852441 cites W2564453477 @default.