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• W2890858822 startingPage "12314" @default.
• W2890858822 abstract "A hydride (H-)-doped bimetallic superatom (HPdAu8)+ was produced by reacting BH4- with an oblate (PdAu8)2+ superatom protected by PPh3. The H atom in (HPdAu8)+ survived during the sequential addition of Au(I)Cl to form an (HPdAu10)3+ superatom, in sharp contrast to the proton release from a H--doped pure gold superatom (HAu9)2+ in the growth process to (Au11)3+. Single-crystal X-ray diffraction analysis and density functional theory calculations on (HPdAu10)3+ showed that the interstitially doped H atom induced a notable deformation of the core." @default.
• W2890858822 created "2018-09-27" @default.
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• W2890858822 date "2018-09-04" @default.
• W2890858822 modified "2023-10-12" @default.
• W2890858822 title "Hydride-Mediated Controlled Growth of a Bimetallic (Pd@Au₈)²⁺ Superatom to a Hydride-Doped (HPd@Au₁₀)³⁺ Superatom" @default.
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• W2890858822 doi "https://doi.org/10.1021/jacs.8b06783" @default.
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